Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx...Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.展开更多
An attempt has been made to study the tailor welded blanks （TWBs） made by friction stir welding （FSW） with five different tool pin profiles. The formability of welded blanks was evaluated at constant FSW process p...An attempt has been made to study the tailor welded blanks （TWBs） made by friction stir welding （FSW） with five different tool pin profiles. The formability of welded blanks was evaluated at constant FSW process parameters. It has been found that the welded blanks with square pin profile tool produced better formability properties as compared to other tool pin profiles. It was found that the pulsating action of the square pin profile is said to be the reason for this improvement. A microstructural evaluation performed on the blanks revealed that the stir zone created by taper cylindrical and stepped cylindrical tools was less homogeneous than that of the square tool, resulting in less formability. The limiting dome height （LDH） of square pin profile tool was found to be 14 mm while those of taper cylindrical and stepped cylindrical tools are 12.5 mm and 12.4 mm, respectively.展开更多
In this study, we have demonstrated the conformational changes to DNA induced by abnormal interactions of copper using circular dichroism, in combination with UV-absorbance and fluorescence spectroscopy. Results confi...In this study, we have demonstrated the conformational changes to DNA induced by abnormal interactions of copper using circular dichroism, in combination with UV-absorbance and fluorescence spectroscopy. Results confirm that binding of copper to bases of DNA in chromatin is concentration dependent. Binding efficiency of Cu2~ ions to DNA is increased in proportion to the degree of unwinding of the double helix induced by denaturation. Altered B-DNA conformation will alter the integrity of DNA which may affect the normal process of DNA replication and transcription. Copper induced DNA damage in the brain may cause neurotoxicity and the neuronal cell death and is implicated in Alzheimer＇s disease and other neurological disorders.展开更多
文摘Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.
基金financial support under the SERC scheme (SR/S3/MERC0110/2009 dated July 30,2010) to Dr M J DAVIDSON
文摘An attempt has been made to study the tailor welded blanks （TWBs） made by friction stir welding （FSW） with five different tool pin profiles. The formability of welded blanks was evaluated at constant FSW process parameters. It has been found that the welded blanks with square pin profile tool produced better formability properties as compared to other tool pin profiles. It was found that the pulsating action of the square pin profile is said to be the reason for this improvement. A microstructural evaluation performed on the blanks revealed that the stir zone created by taper cylindrical and stepped cylindrical tools was less homogeneous than that of the square tool, resulting in less formability. The limiting dome height （LDH） of square pin profile tool was found to be 14 mm while those of taper cylindrical and stepped cylindrical tools are 12.5 mm and 12.4 mm, respectively.
文摘In this study, we have demonstrated the conformational changes to DNA induced by abnormal interactions of copper using circular dichroism, in combination with UV-absorbance and fluorescence spectroscopy. Results confirm that binding of copper to bases of DNA in chromatin is concentration dependent. Binding efficiency of Cu2~ ions to DNA is increased in proportion to the degree of unwinding of the double helix induced by denaturation. Altered B-DNA conformation will alter the integrity of DNA which may affect the normal process of DNA replication and transcription. Copper induced DNA damage in the brain may cause neurotoxicity and the neuronal cell death and is implicated in Alzheimer＇s disease and other neurological disorders.
