In our studies concerning the structure of liquid-vapour interfaces with aqueous mixtures of alcohols,we have shown the importance of local composition fluctuations for superficial mixture properties.We have observed ...In our studies concerning the structure of liquid-vapour interfaces with aqueous mixtures of alcohols,we have shown the importance of local composition fluctuations for superficial mixture properties.We have observed a correlation between the contact angle of the three-phase system liquid-vapour-solid,the variation of the surface tension,and the surface structure factor,whihc is elrated to the local comPosition fluctuations in the transition layer.展开更多
文摘In our studies concerning the structure of liquid-vapour interfaces with aqueous mixtures of alcohols,we have shown the importance of local composition fluctuations for superficial mixture properties.We have observed a correlation between the contact angle of the three-phase system liquid-vapour-solid,the variation of the surface tension,and the surface structure factor,whihc is elrated to the local comPosition fluctuations in the transition layer.