The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a si...The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a single-phase cubic perovskite structure. The compositional dependence of lattice constant, density and microstructural studies show that they vary significantly with La3＋ content. When measured at 10 kHz, all the compositions of SLTFO at room temperature exhibit a high permittivity （about 104） and low dielectric loss （about 10-3）. SLTFO also display minimum dielectric loss within the lower and higher limits of frequency, indicating that the samples are of good quality. It is concluded from the calculated ac conductivity that the conduction is due to mixed polarons hopping. The complex impedance plot exhibits a tendency of forming a single semicircular arc for all compositions, which implies a dominance of grain boundary resistance on the impedance. Impedance parameters were determined by fitting the experimental data with Cole-Cole empirical formula. The results of the present experiment indicate that the lead free SLTFO materials with higher permittivity and lower dielectric loss have possible practical applications.展开更多
Various polycrystalline Ba1-x Lax (Ti0.5 Fe0.5 )O3 are prepared by using the standard solid state reaction technique.Pellet shaped samples prepared from each composition are sintered at 1200℃ for 5 h.X-ray diffractio...Various polycrystalline Ba1-x Lax (Ti0.5 Fe0.5 )O3 are prepared by using the standard solid state reaction technique.Pellet shaped samples prepared from each composition are sintered at 1200℃ for 5 h.X-ray diffraction patterns of these compositions confirm the formation of a single phase perovskite structure.The lattice parameters are decreased but the average grain size increases with the increase of La content.The dielectric constant,dielectric loss and ac conductivity are studied as a function of frequency for various compositions,and their behaviors are explained on the basis of the Maxwell-Wagner model A three-times enhancement of the dielectric constant is observed with the increase of La content.展开更多
Structural and various electrical properties of polycrystalline Ca0.5＋xNd0,5-x（Ti0.5Fe0.5）O3, prepared by standard solid state reaction technique, were studied. Formation of single phase orthorhombic structure of t...Structural and various electrical properties of polycrystalline Ca0.5＋xNd0,5-x（Ti0.5Fe0.5）O3, prepared by standard solid state reaction technique, were studied. Formation of single phase orthorhombic structure of the compositions was confirmed by X-ray diffraction study. The composition dependence of lattice parameters, density and microstructural study show that they vary significantly with Ca content. The dielectric measurements were carried out at room temperature as function of frequency and composition. The experimental results reveal that the dielectric constant （ε′） increases with increasing Ca content. Similar behavior is observed for the dielectric loss （tanδ） and ac conductivity （σac）. In complex impedance analysis it is observed that the real part （Z′） vs imaginary part （Z″） graph exhibits a tendency of formation of a single semicircular arc for each composition of samples. Different parameters were determined by fitting the experimental data in Cole-Cole empirical formula. A dominance of grain boundary resistance （Rgb） is observed. The Rgb decreases with increasing Ca content. The high ε′ observed in present samples are suitable for fabrication of devices.展开更多
基金Project supported by CASR of Bangladesh University of Engineering and Technology(BUET)
文摘The structural and electrical properties of lead free Srx-xLax（Tio.sFeo.5）O3 （SLTFO） prepared by standard solid state reaction technique were studied. The X-ray diffraction analysis confirmed the formation of a single-phase cubic perovskite structure. The compositional dependence of lattice constant, density and microstructural studies show that they vary significantly with La3＋ content. When measured at 10 kHz, all the compositions of SLTFO at room temperature exhibit a high permittivity （about 104） and low dielectric loss （about 10-3）. SLTFO also display minimum dielectric loss within the lower and higher limits of frequency, indicating that the samples are of good quality. It is concluded from the calculated ac conductivity that the conduction is due to mixed polarons hopping. The complex impedance plot exhibits a tendency of forming a single semicircular arc for all compositions, which implies a dominance of grain boundary resistance on the impedance. Impedance parameters were determined by fitting the experimental data with Cole-Cole empirical formula. The results of the present experiment indicate that the lead free SLTFO materials with higher permittivity and lower dielectric loss have possible practical applications.
基金Supported by the CASR of Bangladesh University of Engineering and Technology(BUET).for this research。
文摘Various polycrystalline Ba1-x Lax (Ti0.5 Fe0.5 )O3 are prepared by using the standard solid state reaction technique.Pellet shaped samples prepared from each composition are sintered at 1200℃ for 5 h.X-ray diffraction patterns of these compositions confirm the formation of a single phase perovskite structure.The lattice parameters are decreased but the average grain size increases with the increase of La content.The dielectric constant,dielectric loss and ac conductivity are studied as a function of frequency for various compositions,and their behaviors are explained on the basis of the Maxwell-Wagner model A three-times enhancement of the dielectric constant is observed with the increase of La content.
基金acknowledge CASR of Bangladesh University of Engineering and Technology(BUET) for financial support for this research
文摘Structural and various electrical properties of polycrystalline Ca0.5＋xNd0,5-x（Ti0.5Fe0.5）O3, prepared by standard solid state reaction technique, were studied. Formation of single phase orthorhombic structure of the compositions was confirmed by X-ray diffraction study. The composition dependence of lattice parameters, density and microstructural study show that they vary significantly with Ca content. The dielectric measurements were carried out at room temperature as function of frequency and composition. The experimental results reveal that the dielectric constant （ε′） increases with increasing Ca content. Similar behavior is observed for the dielectric loss （tanδ） and ac conductivity （σac）. In complex impedance analysis it is observed that the real part （Z′） vs imaginary part （Z″） graph exhibits a tendency of formation of a single semicircular arc for each composition of samples. Different parameters were determined by fitting the experimental data in Cole-Cole empirical formula. A dominance of grain boundary resistance （Rgb） is observed. The Rgb decreases with increasing Ca content. The high ε′ observed in present samples are suitable for fabrication of devices.
