In this study,a novel eutectic-reaction brazing of Al_(0.3)CoCrFeNi high-entropy alloys(HEAs)^(1)was investigated with a design of laminated Ni/Nb/Ni interlayers.The typical Al_(0.3)CoCrFeNi brazing seam consisted of ...In this study,a novel eutectic-reaction brazing of Al_(0.3)CoCrFeNi high-entropy alloys(HEAs)^(1)was investigated with a design of laminated Ni/Nb/Ni interlayers.The typical Al_(0.3)CoCrFeNi brazing seam consisted of proeutecticγ,the lamellar eutectic structure composed of face-centered cubic(FCC)phase(eutecticγ)and C14 Laves,as well as a few amounts of Nb based solid solution.A high density of nanoscale ordered L1_(2)(γ)phase was precipitated withinγphase matrix.With the brazing temperature raised from 1200 to 1320℃,the dissolution volume of Al_(0.3)CoCrFeNi alloy into Ni-Nb liquid was increased.The microstructure of the brazing seam changed from hypereutectic(blocky Laves+γphase)to eutectic(Laves+eutecticγ)to hypoeutectic structures(proeutecticγ+Laves/γeutectic structure).The shear strength of joints was increased gradually due to the formation of eutectic lamellae and the cellular growth of proeutecticγphase.The maximum shear strength of the joint brazed at 1320℃for 10 min was up to 592 MPa,reaching 95%of the base metal.The joint mainly ruptured in the soft proeutecticγphase in a ductile fracture mode.展开更多
基金the National Natural Science Foundation of China(Nos.52175307,51775138 and U1737205)the Taishan Scholars Foundation of Shandong Province(No.tsqn201812128)。
文摘In this study,a novel eutectic-reaction brazing of Al_(0.3)CoCrFeNi high-entropy alloys(HEAs)^(1)was investigated with a design of laminated Ni/Nb/Ni interlayers.The typical Al_(0.3)CoCrFeNi brazing seam consisted of proeutecticγ,the lamellar eutectic structure composed of face-centered cubic(FCC)phase(eutecticγ)and C14 Laves,as well as a few amounts of Nb based solid solution.A high density of nanoscale ordered L1_(2)(γ)phase was precipitated withinγphase matrix.With the brazing temperature raised from 1200 to 1320℃,the dissolution volume of Al_(0.3)CoCrFeNi alloy into Ni-Nb liquid was increased.The microstructure of the brazing seam changed from hypereutectic(blocky Laves+γphase)to eutectic(Laves+eutecticγ)to hypoeutectic structures(proeutecticγ+Laves/γeutectic structure).The shear strength of joints was increased gradually due to the formation of eutectic lamellae and the cellular growth of proeutecticγphase.The maximum shear strength of the joint brazed at 1320℃for 10 min was up to 592 MPa,reaching 95%of the base metal.The joint mainly ruptured in the soft proeutecticγphase in a ductile fracture mode.