In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (...In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A ^1 Π,v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.展开更多
In order to study the collisional quantum interference (CQI) on rotational energy transfer in atom-diatom system, we have studied the relation of the integral interference angle and differential interference angle i...In order to study the collisional quantum interference (CQI) on rotational energy transfer in atom-diatom system, we have studied the relation of the integral interference angle and differential interference angle in Naq-Na2 (A1 ∑u^+,v=8-b^3∏0u,v=14) collision system. In this paper, based on the first-Born approximation of timedependent perturbation theory and taking into accounts the anisotropic effect of Lennard-Jones interaction potentials, we present a theoretical model of collisional quantum interference in intramolecular rotational energy transfer, and a relationship between differential and integral interference angles.展开更多
Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the inter...Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14)-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and "straight-line" trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.展开更多
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘In our previous theoretical studies [Meng-Tao Sun, Yong-Qing Lee, and Feng-Cai Ma, Chem. Phys.Left. 371 (2003) 342], we have reported the quantum interference on collision-induced rotational energy transfer on CO (A ^1 Π,v = 3) with inert gases, which originates from the difference between the two A-related collision potential energy surfaces. The interference angle, which measures the degree of coherence, is presented in this paper. Based on the time-dependent first order Born approximation, taking into account the anisotropic Lennard-Jones interaction potentials, the relation of the interference angle with the factors, including experimental temperature, partner, and rotational quantum number, are obtained. The changing tendencies with them are discussed. This theoretical model is important to understanding and performing this kind of experiment.
基金Supported by the National Natural Science Foundation of China under Grant No.10374040the Foundation of the Educational Department of Liaoning Province under Grant Nos.2008290 and 20060347
文摘In order to study the collisional quantum interference (CQI) on rotational energy transfer in atom-diatom system, we have studied the relation of the integral interference angle and differential interference angle in Naq-Na2 (A1 ∑u^+,v=8-b^3∏0u,v=14) collision system. In this paper, based on the first-Born approximation of timedependent perturbation theory and taking into accounts the anisotropic effect of Lennard-Jones interaction potentials, we present a theoretical model of collisional quantum interference in intramolecular rotational energy transfer, and a relationship between differential and integral interference angles.
基金The project supported by National Natural Science Foundation of China under Grant No. 10374040
文摘Collisional quantum interference (CQI) on rotational energy transfer was observed in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14) system in collision with Na [Chem. Phys. Lett. 318 (2000) 107], and the degree of the interference was measured. The integral interference angle was obtaJned through theoretical calculation. We will research the factors that have effect on collisional quantum interference on rotational energy transfer in Na2(A^1∑u^+,ν=8~b^3∏0u,ν=14)-Na system. Basing on the time-dependent first order Born approximation, and taking into account the anlsotroplc Lennard Jones interaction potentials and "straight-line" trajectory approximation, we obtain the factors that have effect on CQI in Na2-Na system, and obtain the relation between the integral interference angle and rotational quantum number.