C_(3)N_(4),C_(3)N_(4)@Ti_(3)C_(2)and W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres were successfully prepared by using SiO_(2)template followed by gradual deposition method.The degradation of phenol solution and p...C_(3)N_(4),C_(3)N_(4)@Ti_(3)C_(2)and W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres were successfully prepared by using SiO_(2)template followed by gradual deposition method.The degradation of phenol solution and photolysis ability were tested to characterize its photocatalytic activity.Compared with the single-shelled C_(3)N_(4)and C_(3)N_(4)@Ti_(3)C_(2)hollow spheres,double-shelled W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres possessed larger surface area and fast charge separation efficiency,exhibiting about 8.9 times and 4.0 times higher H_(2)evolution than those of C_(3)N_(4),C_(3)N_(4)@Ti_(3)C_(2)hollow spheres,respectively.The photocatalytic mechanism of the W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres were carefully investigated according to the results of morphology design and photoelectric performance.A Z scheme mechanism based on the construction of heterojunctions was proposed to explain the improvement of photocatalytic performance.This new charge transfer mechanism appears to greatly inhibit the recombination of electrons/holes during the charge transfer process,while maintaining its strong hydrogen reduction ability,resulting in a higher photocatalytic performance.展开更多
Both the level 2.5 Mellor-Yamada turbulence closure scheme （MY） and K-profile parameterization （KPP） are popularly used by the ocean modeling community. The MY and the KPP are improved through including the non-br...Both the level 2.5 Mellor-Yamada turbulence closure scheme （MY） and K-profile parameterization （KPP） are popularly used by the ocean modeling community. The MY and the KPP are improved through including the non-breaking surface wave-induced vertical mixing （Bv）, and the improved schemes were tested by using continuous data at the Papa ocean weather station （OWS） during 1961-1965. The numerical results showed that the Bv can make the temperature simulations fit much better with the continuous data from Papa Sta- tion. The two improved schemes overcame the shortcomings of predicting too shallow upper mixed layer depth and consequently overheated sea surface temperature during summertime, which are in fact com- mon problems for all turbulence closure models. Statistical analysis showed that the Bv effectively reduced the mean absolute error and root mean square error of the upper layer temperature and increased the corre- lation coefficient between simulation and the observation. Furthermore, the performance of vertical mixing induced by shear instability and the Bv is also compared. Both the temperature structure and its seasonal cycle significantly improved by including the Bv, regardless of whether shear instability was included or not, especially for the KPP mixing scheme, which suggested that Bv played a dominant role in the upper ocean where the mean current was relatively weak, such as at Papa Station. These results may provide a clue to improve ocean circulation models.展开更多
The doublesex and mab-3 related transcription factor(DMRT)gene family is conserved from invertebrates to humans.The functions of DMRT are mainly involved in sex development and the formation of many tissues and organs...The doublesex and mab-3 related transcription factor(DMRT)gene family is conserved from invertebrates to humans.The functions of DMRT are mainly involved in sex development and the formation of many tissues and organs.In this study,a DM(Doublesex/Mab-3-domain gene was identified in the mud crab Scylla paramamosain,and was named SpDMRT99B because of its many similarities to arthropod DMRT99B and phylogenetically close relationship with arthropod DMRT99B.The cDNA of SpDMRT99B gene is 1249 bp in length,encoding 224 amino acids.From 254 bp to 928 bp there is a conserved DM domain.No transmembrane domain was identified.Through multiple amino acid alignment and phylogenetic tree analysis,the closest gene to SpDMRT99B is Eriocheir sinensis DMRT99B,followed by Macrobrachium rosenbergii and Drosophila melanogaster DMRT99B.The expressions of the gene were characterized in different tissues of female and male crabs during early development period of crab individuals,as well as in different development periods of gonads.The results showed that SpDMRT99B gene is significantly highly expressed in testis than in ovary and other tissues.The expression level of SpDMRT99B in testis at different stages is significantly higher than that in ovary,and it is particularly highly expressed in immature testis.In early developmental stages of larvae,the expressions of SpDMRT99B remain at a low level and reach a peak at zoea stage I when the body segments shape up.It is speculated that SpDMRT99B gene might be involved in the gonadal development process and somitogenesis of S.paramamosain.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.91963207 and 12075174)。
文摘C_(3)N_(4),C_(3)N_(4)@Ti_(3)C_(2)and W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres were successfully prepared by using SiO_(2)template followed by gradual deposition method.The degradation of phenol solution and photolysis ability were tested to characterize its photocatalytic activity.Compared with the single-shelled C_(3)N_(4)and C_(3)N_(4)@Ti_(3)C_(2)hollow spheres,double-shelled W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres possessed larger surface area and fast charge separation efficiency,exhibiting about 8.9 times and 4.0 times higher H_(2)evolution than those of C_(3)N_(4),C_(3)N_(4)@Ti_(3)C_(2)hollow spheres,respectively.The photocatalytic mechanism of the W_(18)O_(49)@C_(3)N_(4)@Ti_(3)C_(2)hollow spheres were carefully investigated according to the results of morphology design and photoelectric performance.A Z scheme mechanism based on the construction of heterojunctions was proposed to explain the improvement of photocatalytic performance.This new charge transfer mechanism appears to greatly inhibit the recombination of electrons/holes during the charge transfer process,while maintaining its strong hydrogen reduction ability,resulting in a higher photocatalytic performance.
基金The National Basic Research Program("973"Program)of China under contract No.2010CB950303the Public Science and Technology Research Funds Projects of Ocean under contract No.201105019the National Key Technology Research and Development Program of China under contract No.2011BAC03B02
文摘Both the level 2.5 Mellor-Yamada turbulence closure scheme （MY） and K-profile parameterization （KPP） are popularly used by the ocean modeling community. The MY and the KPP are improved through including the non-breaking surface wave-induced vertical mixing （Bv）, and the improved schemes were tested by using continuous data at the Papa ocean weather station （OWS） during 1961-1965. The numerical results showed that the Bv can make the temperature simulations fit much better with the continuous data from Papa Sta- tion. The two improved schemes overcame the shortcomings of predicting too shallow upper mixed layer depth and consequently overheated sea surface temperature during summertime, which are in fact com- mon problems for all turbulence closure models. Statistical analysis showed that the Bv effectively reduced the mean absolute error and root mean square error of the upper layer temperature and increased the corre- lation coefficient between simulation and the observation. Furthermore, the performance of vertical mixing induced by shear instability and the Bv is also compared. Both the temperature structure and its seasonal cycle significantly improved by including the Bv, regardless of whether shear instability was included or not, especially for the KPP mixing scheme, which suggested that Bv played a dominant role in the upper ocean where the mean current was relatively weak, such as at Papa Station. These results may provide a clue to improve ocean circulation models.
基金the National Natural Science Foundation of China(No.31772837)the National Key Research&Development Program of China(No.2018YF D0900201)+2 种基金the Science and Technology Project of Guang-dong Province(No.2018A050506080)the Shantou Uni-versity Scientific Research Foundation for Talents(No.NTF17006)the Program for Innovation and Enhance-ment of School of Department of Education of Guang-dong Province(No.2017KCXTD014).
文摘The doublesex and mab-3 related transcription factor(DMRT)gene family is conserved from invertebrates to humans.The functions of DMRT are mainly involved in sex development and the formation of many tissues and organs.In this study,a DM(Doublesex/Mab-3-domain gene was identified in the mud crab Scylla paramamosain,and was named SpDMRT99B because of its many similarities to arthropod DMRT99B and phylogenetically close relationship with arthropod DMRT99B.The cDNA of SpDMRT99B gene is 1249 bp in length,encoding 224 amino acids.From 254 bp to 928 bp there is a conserved DM domain.No transmembrane domain was identified.Through multiple amino acid alignment and phylogenetic tree analysis,the closest gene to SpDMRT99B is Eriocheir sinensis DMRT99B,followed by Macrobrachium rosenbergii and Drosophila melanogaster DMRT99B.The expressions of the gene were characterized in different tissues of female and male crabs during early development period of crab individuals,as well as in different development periods of gonads.The results showed that SpDMRT99B gene is significantly highly expressed in testis than in ovary and other tissues.The expression level of SpDMRT99B in testis at different stages is significantly higher than that in ovary,and it is particularly highly expressed in immature testis.In early developmental stages of larvae,the expressions of SpDMRT99B remain at a low level and reach a peak at zoea stage I when the body segments shape up.It is speculated that SpDMRT99B gene might be involved in the gonadal development process and somitogenesis of S.paramamosain.
