本实验探究不同因素对高温条件下芝麻林素转化为芝麻酚的影响及其转化动力学,并通过液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry,LC-MS/MS)分析相关转化路径。结果表明:丙三醇是芝麻林素转化为芝麻酚的理想介质...本实验探究不同因素对高温条件下芝麻林素转化为芝麻酚的影响及其转化动力学,并通过液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry,LC-MS/MS)分析相关转化路径。结果表明:丙三醇是芝麻林素转化为芝麻酚的理想介质,反应温度和反应时间对芝麻酚生成率影响显著;在160~200℃范围内,芝麻林素的转化符合一级动力学方程特征,且反应速率常数与温度呈正相关,半衰期和十分之一衰期与温度呈负相关,通过阿伦尼乌斯方程计算出该反应活化能为(104.50±4.32)kJ/mol;LC-MS/MS分析结果表明以芝麻林素为底物的反应系统包括芝麻酚的生成和转化两条转化路径。展开更多
The regulation of the National Significant Seismic Monitoring and Protection Regions(NSSMPR for short) is defined by the Law of the Peoples Republic of China on Protecting Against and Mitigating Earthquake Disasters.T...The regulation of the National Significant Seismic Monitoring and Protection Regions(NSSMPR for short) is defined by the Law of the Peoples Republic of China on Protecting Against and Mitigating Earthquake Disasters.The first stage of implementation of the regulation of NSSMPR in the Chinese mainland was finished from 1996 to 2005.The second stage is being carried on from 2006 to 2020.With the support of the National Social Science Foundation,this paper follows up and evaluates the implementation of the regulation of NSSMPR from 1996 to 2012 in the Chinese mainland.Based on analysis of earthquake examples and investigation data,we find that the effect of disaster mitigation is good,and on this basis,some suggestions are proposed to improve the regulation of NSSMPR.展开更多
文摘本实验探究不同因素对高温条件下芝麻林素转化为芝麻酚的影响及其转化动力学,并通过液相色谱-串联质谱(liquid chromatography-tandem mass spectrometry,LC-MS/MS)分析相关转化路径。结果表明:丙三醇是芝麻林素转化为芝麻酚的理想介质,反应温度和反应时间对芝麻酚生成率影响显著;在160~200℃范围内,芝麻林素的转化符合一级动力学方程特征,且反应速率常数与温度呈正相关,半衰期和十分之一衰期与温度呈负相关,通过阿伦尼乌斯方程计算出该反应活化能为(104.50±4.32)kJ/mol;LC-MS/MS分析结果表明以芝麻林素为底物的反应系统包括芝麻酚的生成和转化两条转化路径。
基金sponsored by the National Social Science Foundation of China"Research on the Status,Efficiencies and the Policy on the National Significant Seismic Monitoring and Protection Regions"(11&ZD054)
文摘The regulation of the National Significant Seismic Monitoring and Protection Regions(NSSMPR for short) is defined by the Law of the Peoples Republic of China on Protecting Against and Mitigating Earthquake Disasters.The first stage of implementation of the regulation of NSSMPR in the Chinese mainland was finished from 1996 to 2005.The second stage is being carried on from 2006 to 2020.With the support of the National Social Science Foundation,this paper follows up and evaluates the implementation of the regulation of NSSMPR from 1996 to 2012 in the Chinese mainland.Based on analysis of earthquake examples and investigation data,we find that the effect of disaster mitigation is good,and on this basis,some suggestions are proposed to improve the regulation of NSSMPR.