According to the adsorption-desorption characteristics of coalbed gas and analysis of various experimental data, this paper proposes that the generation of secondary biogenic gas （SBG） and its mixing of with the res...According to the adsorption-desorption characteristics of coalbed gas and analysis of various experimental data, this paper proposes that the generation of secondary biogenic gas （SBG） and its mixing of with the residual thermogenic gas at an early stage inevitably lead to secondary changes of the thermogenic gas and various geochemical additive effects. Experimental results also show that the fractionation of the carbon isotope of methane of coal core desorption gas changes very little; the δ13C1 value of the mixed gas of biogenic and thermogenic gases is between the δ13C1 values of the two ＂original＂ gases, and the value is determined by the carbon isotopic compositions and mixing proportions of the two ＂original＂ methanes. Therefore this paper proposes that the study on the secondary changes of the thermogenic gas and various additive effects is a new effective way to study and identify SBG. Herein, a systematic example of research on the coalbed gas （Huainan coalbed gas） is further conducted, revealing a series of secondary changes and additive effects, the main characteristics and markers of which are： （1） the contents of CO2 and heavy-hydrocarbons decrease significantly; （2） the content of CH4 increases and the gas becomes drier; （3） the δ13C and δD values of methane decrease significantly and tend to have biogenetic characteristics; and （4） the values of 513C2 and δ13Cc02 grow higher. These isotopic values also change with the degradation degrees by microbes and mixing proportions of the two kinds of gases in different locations. There exists a negative correlation between the △13C1 It＇S δ13Cco2 values. The δ13Cc2-c1 values obviously become higher. The distributions of the △δ^13Cco2-C1 values are within certain limits and show regularity. There exist a positive correlation between the N2 versus Ar contents, and a negative correlation between the N2 versus CH4 contents, indicating the down forward infiltration of the surface water containing air. These are important markers of the generation and existence of SBG .展开更多
Pollen records from the Chinese Loess Plateau revealed a detailed history of vegetation variation and associated climate changes during the last 13.0 ka BP. Before 12.1 ka BP, steppe or desert-steppe vegetation domina...Pollen records from the Chinese Loess Plateau revealed a detailed history of vegetation variation and associated climate changes during the last 13.0 ka BP. Before 12.1 ka BP, steppe or desert-steppe vegetation dominated landscape then was replaced by a coniferous forest under a generally wet climate （12.1-11.0 ka BP）. The vegetation was deteriorated into steppe landscape and further into a desert-steppe landscape between 11.0 and 9.8 ka BP. After a brief episode of a cool and wet climate （9.8-9.6 ka BP）, a relatively mild and dry condition prevailed during the early Holocene （9.6-7.6 ka BP）. The most favourable climate of warm and humid period occurred during mid-Holocene （7.6-4.0 ka BP） marked by forest-steppe landscape and vegetation alternatively changed between steppe and desert-steppe from -4.0 to -1.0 ka BP.展开更多
The Late Miocene and Pliocene are the key periods for understanding the origin and development of the present Asian monsoon circulations and ecologic environ-ments. Here we present a pollen record from Chaona Red Clay...The Late Miocene and Pliocene are the key periods for understanding the origin and development of the present Asian monsoon circulations and ecologic environ-ments. Here we present a pollen record from Chaona Red Clay section located in the central Loess Plateau in attempt to establish the histories of vegetation and associated climate changes between 8.10 and 2.60 Ma. Our results show that Gramineae-dominated woodland-grasslands developed in this region with Cedrus- and Pinus-characterized montane coniferous forests distributing in higher elevations from 8.10 to 6.73 Ma, probably suggesting a semi-humid climate in a warm-temperate zone. A subsequent expansion of Ulmus- dominated deciduous forests and a synchronous increase of Gramineae-dominated grassland reflect a warmer and more humid climate between 6.73 and 5.67 Ma. The vegetation changed to an Artemisia- and Gramineae-characterized steppe in lower elevations and to a coniferous forest in higher elevations from 5.67 to 3.71 Ma, implying probably a warm and semiarid climate in lowland and hill, and a colder and moister climate in mountain. During this period, a consider-able warmer and more humid climate occurred between 4.61 and 4.07 Ma as indicated by pollen assemblages. The period between 3.71 and 2.58 Ma was characterized by the disap-pearance of Cedrus and Tsuga and also by an abrupt expan-sion of Cupressaceae, reflecting a drastic enhancement of monsoon-related climatic seasonality.展开更多
基金supported by the Chinese Natural Science Foundation Project(No.41172107 and No.40872096)the 973 National Project(No.2002CB211701)
文摘According to the adsorption-desorption characteristics of coalbed gas and analysis of various experimental data, this paper proposes that the generation of secondary biogenic gas （SBG） and its mixing of with the residual thermogenic gas at an early stage inevitably lead to secondary changes of the thermogenic gas and various geochemical additive effects. Experimental results also show that the fractionation of the carbon isotope of methane of coal core desorption gas changes very little; the δ13C1 value of the mixed gas of biogenic and thermogenic gases is between the δ13C1 values of the two ＂original＂ gases, and the value is determined by the carbon isotopic compositions and mixing proportions of the two ＂original＂ methanes. Therefore this paper proposes that the study on the secondary changes of the thermogenic gas and various additive effects is a new effective way to study and identify SBG. Herein, a systematic example of research on the coalbed gas （Huainan coalbed gas） is further conducted, revealing a series of secondary changes and additive effects, the main characteristics and markers of which are： （1） the contents of CO2 and heavy-hydrocarbons decrease significantly; （2） the content of CH4 increases and the gas becomes drier; （3） the δ13C and δD values of methane decrease significantly and tend to have biogenetic characteristics; and （4） the values of 513C2 and δ13Cc02 grow higher. These isotopic values also change with the degradation degrees by microbes and mixing proportions of the two kinds of gases in different locations. There exists a negative correlation between the △13C1 It＇S δ13Cco2 values. The δ13Cc2-c1 values obviously become higher. The distributions of the △δ^13Cco2-C1 values are within certain limits and show regularity. There exist a positive correlation between the N2 versus Ar contents, and a negative correlation between the N2 versus CH4 contents, indicating the down forward infiltration of the surface water containing air. These are important markers of the generation and existence of SBG .
基金National Science Fund for Distinguished Young Scholars, 40025105 National Natural Science Foundation of China, No. 40331012+3 种基金 NSF Project, No.EAR 0402509 No.BCS 00-78557 Doctoral Fund from Southwest University, No. 104220-20710904 CSTC, No.2009BB7112
文摘Pollen records from the Chinese Loess Plateau revealed a detailed history of vegetation variation and associated climate changes during the last 13.0 ka BP. Before 12.1 ka BP, steppe or desert-steppe vegetation dominated landscape then was replaced by a coniferous forest under a generally wet climate （12.1-11.0 ka BP）. The vegetation was deteriorated into steppe landscape and further into a desert-steppe landscape between 11.0 and 9.8 ka BP. After a brief episode of a cool and wet climate （9.8-9.6 ka BP）, a relatively mild and dry condition prevailed during the early Holocene （9.6-7.6 ka BP）. The most favourable climate of warm and humid period occurred during mid-Holocene （7.6-4.0 ka BP） marked by forest-steppe landscape and vegetation alternatively changed between steppe and desert-steppe from -4.0 to -1.0 ka BP.
基金This work was co-supported by The NSFC Group Funds (Grant Nos. 40121303, 40171094 and 40421101) ；CSA“Hun-dred Talent Projects" (Grant No. Renjiaozi [2000]05).
文摘The Late Miocene and Pliocene are the key periods for understanding the origin and development of the present Asian monsoon circulations and ecologic environ-ments. Here we present a pollen record from Chaona Red Clay section located in the central Loess Plateau in attempt to establish the histories of vegetation and associated climate changes between 8.10 and 2.60 Ma. Our results show that Gramineae-dominated woodland-grasslands developed in this region with Cedrus- and Pinus-characterized montane coniferous forests distributing in higher elevations from 8.10 to 6.73 Ma, probably suggesting a semi-humid climate in a warm-temperate zone. A subsequent expansion of Ulmus- dominated deciduous forests and a synchronous increase of Gramineae-dominated grassland reflect a warmer and more humid climate between 6.73 and 5.67 Ma. The vegetation changed to an Artemisia- and Gramineae-characterized steppe in lower elevations and to a coniferous forest in higher elevations from 5.67 to 3.71 Ma, implying probably a warm and semiarid climate in lowland and hill, and a colder and moister climate in mountain. During this period, a consider-able warmer and more humid climate occurred between 4.61 and 4.07 Ma as indicated by pollen assemblages. The period between 3.71 and 2.58 Ma was characterized by the disap-pearance of Cedrus and Tsuga and also by an abrupt expan-sion of Cupressaceae, reflecting a drastic enhancement of monsoon-related climatic seasonality.
