The orsano-inorganic hybrid compound [ Ni（phen）3] [ （H2W12O40） { Ni（phen）2H2O} { Ni（trien） } ]·2H2O was synthesized from Na2 WO4·2H2O, NiSO4·6H2O, CH3COOK, triethylenetetramine and 1,10-phenanth...The orsano-inorganic hybrid compound [ Ni（phen）3] [ （H2W12O40） { Ni（phen）2H2O} { Ni（trien） } ]·2H2O was synthesized from Na2 WO4·2H2O, NiSO4·6H2O, CH3COOK, triethylenetetramine and 1,10-phenanthroline in water by the hydrothermal reaction, and characterized by IR, X-ray single crystal diffraction, and TG-DTA analysis. This compound crystallized in the monoclinic system, space group P2 （1）/n, with lattice constants： a =1.80998 （6） nm, b =2.36504（8） nm, c =2.29199（7） nm,β= 110.2220（10）°, V=9.2065（5） nm, Z=4. Final R indices R1=0.0532. ωR2=0.1295. The compound is decomposed at 593℃.展开更多
文摘The orsano-inorganic hybrid compound [ Ni（phen）3] [ （H2W12O40） { Ni（phen）2H2O} { Ni（trien） } ]·2H2O was synthesized from Na2 WO4·2H2O, NiSO4·6H2O, CH3COOK, triethylenetetramine and 1,10-phenanthroline in water by the hydrothermal reaction, and characterized by IR, X-ray single crystal diffraction, and TG-DTA analysis. This compound crystallized in the monoclinic system, space group P2 （1）/n, with lattice constants： a =1.80998 （6） nm, b =2.36504（8） nm, c =2.29199（7） nm,β= 110.2220（10）°, V=9.2065（5） nm, Z=4. Final R indices R1=0.0532. ωR2=0.1295. The compound is decomposed at 593℃.
