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含双硫脲基团分子钳在非极性溶剂中识别中性分子
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作者 陈珊 陈志林 +5 位作者 胡琼 蒙艳双 黄悦 陶萍芳 卢丽如 黄国保 《有机化学》 SCIE CAS CSCD 北大核心 2024年第1期277-281,共5页
以蒽为原料,通过一系列有机反应高效合成了三种不同的含双硫脲基团的分子钳化合物,通过熔点,1H NMR,13C NMR和HRMS进行结构表征和确证,并采用荧光光谱法详细研究了分子钳在非极性环境下对几种中性分子的识别行为.测试结果表明,分子钳9,... 以蒽为原料,通过一系列有机反应高效合成了三种不同的含双硫脲基团的分子钳化合物,通过熔点,1H NMR,13C NMR和HRMS进行结构表征和确证,并采用荧光光谱法详细研究了分子钳在非极性环境下对几种中性分子的识别行为.测试结果表明,分子钳9,10-二(3,5-三氟甲基苯基-硫脲)蒽(T-3)对几种客体分子有较好的识别能力.详细讨论了分子间氢键与多种C—H…π相互作用力在分子识别中的协同作用. 展开更多
关键词 双硫脲分子钳 合成 识别 中性分子
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One Step Hydrothermal Synthesis of Flower-shaped CO3O4 Nanorods on Nickel Foam as Supercapacitor Materials and Their Excellent Electrochemical Performance
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作者 WANG Chen meng yanshuang +2 位作者 WANG Lei ZHU Fuliang ZHANG Yue 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2018年第6期882-886,共5页
Flower-shaped Co3O4 nanorods directly grown on nickel foam(Co3O4/NF) were prepared by one step hy-drothermal method at low temperature. Co3O4 nanorods are directly connected with the nickel foam, and no binder is ne... Flower-shaped Co3O4 nanorods directly grown on nickel foam(Co3O4/NF) were prepared by one step hy-drothermal method at low temperature. Co3O4 nanorods are directly connected with the nickel foam, and no binder is needed as an additive, so the Co3O4NF electrode has good electrical conductivity. This flower-shaped structure makes larger surface area of Co3O4 nanorods that exposes to the electrolyte, thus promoting the redox reaction. The Co3O4/NF electrode shows a high specific capacitance of 2005.34 F/g at the current density of 0.5 A/g and a high capacitance retention of 98.0% after 5000 cycles. The high superior capacitive performance with high specific capacitance and the excellent cyclic performance indicate that the one step hydrothermal method has great potential application in supercapacitors. 展开更多
关键词 SUPERCAPACITOR Co3O4/NF HYDROTHERMAL Nanorod
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