In order to distinguish the source and migration direction of natural gas by geochemical characteristics of butane,the components and carbon isotopes of natural gas from major hydrocarbonbearing basins in China were a...In order to distinguish the source and migration direction of natural gas by geochemical characteristics of butane,the components and carbon isotopes of natural gas from major hydrocarbonbearing basins in China were analyzed.The results showed that：（1） Oil-type gas has i-C 4 /n-C 4 0.8,δ 13 C butane -28‰,δ 13 C i-butane -27‰,δ 13 C n-butane -28.5‰,whereas coal-type gas has i-C 4 /n-C 4 0.8,δ 13 C butane -25.5‰,δ 13 C i-butane -24‰,δ 13 C n-butane -26‰.（2） When δ 13 C i-butane-δ 13 C n-butane is greater than 0,the maturity of oil-type gas is generally more than 2.4% and that of coal-type gas is greater than 1.4%,whereas when the difference is less than 0,the maturity of oil-type gas is generally less than 1.1% and that of coal-type gas is less than 0.8%.（3） When natural gas migrates through dense cap rocks,the value of i-C 4 /n-C 4 increases,whereas when it migrates laterally along a reservoir,the value of i-C 4 /n-C 4 decreases.（4） Sapropelic transition zone gas with composition and carbon isotopic signatures similar to those of oil-type gas in the low thermal evolution stage is found to have a relatively high butane content.（5） The values of i-C 4 /n-C 4 and δ 13 C n-butane δ 13 C i-butane of gas which has suffered biological degradation are significantly higher than those obtained from thermogenic and bio-thermocatalytic transition zone gas.Thus,natural gas of different genetic types can be recognized through component analysis and carbon isotopic signatures of butane,the natural gas maturity can be estimated from the difference in carbon isotopic content between isobutane and n-butane,and the migration direction of natural gas can be determined from i-C 4 /n-C 4 ratios and transport conditions,which can also be used to thermogenic and bio-thermocatalytic transition zone gas.展开更多
Objective The Mengyejing potash deposit in the Simao Basin is the only producing area of solid potash at present in China. There is still controversy about the material source and distribution of the potash in this d...Objective The Mengyejing potash deposit in the Simao Basin is the only producing area of solid potash at present in China. There is still controversy about the material source and distribution of the potash in this deposit （Shen Lijian et al., 2017）, which has influenced not only the prospecting direction and efficiency but also the understanding of the control of Tethys tectonic evolution on the formation and distribution of the mineral resources. This work analyzed the Sr isotope geochemical characteristics of evaporites from core samples in the well MZK-3 in order to further clarify the material source and to explore the potash distribution in the Simao Basin.展开更多
The Lanping−Simao Basin is located on the southeastern Tibetan Plateau,China,and contains massive evaporites.The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectoni...The Lanping−Simao Basin is located on the southeastern Tibetan Plateau,China,and contains massive evaporites.The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectonic movement.Forty halite samples from borehole MK-3 in the Mengyejing area of the basin were collected and analyzed using XRD,Cl-Sr isotopes and chemical compositions to trace the origin of the evaporites in the basin.The Br×10^(3)/Cl ratios of the halite samples are between 0 and 0.55,most of which are synchronized with the law of seawater evaporation and at the stage of halite precipitation from seawater,indicating that the evaporites are mainly of marine origin.The^(87)Sr/^(86)Sr ratios range from 0.707489 to 0.711279;after correction,the^(87)Sr/^(86)Sr 145 Ma ratios range from 0.704721 to 0.707611,equivalent with the 87Sr/86Sr ratios of seawater at 145 Ma,indicating a marine origin.The decay of 87Rb in the evaporite during deposition,change of the depositional environment and the unsealed environment at a later period resulted in the present^(87)Sr/^(86)Sr ratios of some samples being high.The δ^(37)Cl value compositions range from−0.38‰to 0.83‰,which is consistent with the δ^(37)Cl value composition of the world marine halite(−0.6‰to 0.4‰),further confirming that seawater is the main origin.In addition,the high δ^(37)Cl value of some samples at the boundary of the upper and lower evaporite layers might be related to the influence of δ^(37)Cl-rich brine and the incomplete dissolution of the halite.展开更多
基金supported by NSFC (Grant No. 41202100)the National Science and Technology Major Projects(Grant No. 2008ZX05007-003)
文摘In order to distinguish the source and migration direction of natural gas by geochemical characteristics of butane,the components and carbon isotopes of natural gas from major hydrocarbonbearing basins in China were analyzed.The results showed that：（1） Oil-type gas has i-C 4 /n-C 4 0.8,δ 13 C butane -28‰,δ 13 C i-butane -27‰,δ 13 C n-butane -28.5‰,whereas coal-type gas has i-C 4 /n-C 4 0.8,δ 13 C butane -25.5‰,δ 13 C i-butane -24‰,δ 13 C n-butane -26‰.（2） When δ 13 C i-butane-δ 13 C n-butane is greater than 0,the maturity of oil-type gas is generally more than 2.4% and that of coal-type gas is greater than 1.4%,whereas when the difference is less than 0,the maturity of oil-type gas is generally less than 1.1% and that of coal-type gas is less than 0.8%.（3） When natural gas migrates through dense cap rocks,the value of i-C 4 /n-C 4 increases,whereas when it migrates laterally along a reservoir,the value of i-C 4 /n-C 4 decreases.（4） Sapropelic transition zone gas with composition and carbon isotopic signatures similar to those of oil-type gas in the low thermal evolution stage is found to have a relatively high butane content.（5） The values of i-C 4 /n-C 4 and δ 13 C n-butane δ 13 C i-butane of gas which has suffered biological degradation are significantly higher than those obtained from thermogenic and bio-thermocatalytic transition zone gas.Thus,natural gas of different genetic types can be recognized through component analysis and carbon isotopic signatures of butane,the natural gas maturity can be estimated from the difference in carbon isotopic content between isobutane and n-butane,and the migration direction of natural gas can be determined from i-C 4 /n-C 4 ratios and transport conditions,which can also be used to thermogenic and bio-thermocatalytic transition zone gas.
基金supported by the"national Key R&D Program of China"(grant No.2017YFC0602801)geological survey project of"Investigation and Evaluation of the Potash Deposit Prospect in West China"(grant No.DD20160054)
文摘Objective The Mengyejing potash deposit in the Simao Basin is the only producing area of solid potash at present in China. There is still controversy about the material source and distribution of the potash in this deposit （Shen Lijian et al., 2017）, which has influenced not only the prospecting direction and efficiency but also the understanding of the control of Tethys tectonic evolution on the formation and distribution of the mineral resources. This work analyzed the Sr isotope geochemical characteristics of evaporites from core samples in the well MZK-3 in order to further clarify the material source and to explore the potash distribution in the Simao Basin.
基金supported by the National Natural Science Foundation of China(Grant No.U1407207)the project of China Geological Survey(Grant No.DD20201115).
文摘The Lanping−Simao Basin is located on the southeastern Tibetan Plateau,China,and contains massive evaporites.The origin of evaporites in the basin has been hotly debated because of the strong transformation by tectonic movement.Forty halite samples from borehole MK-3 in the Mengyejing area of the basin were collected and analyzed using XRD,Cl-Sr isotopes and chemical compositions to trace the origin of the evaporites in the basin.The Br×10^(3)/Cl ratios of the halite samples are between 0 and 0.55,most of which are synchronized with the law of seawater evaporation and at the stage of halite precipitation from seawater,indicating that the evaporites are mainly of marine origin.The^(87)Sr/^(86)Sr ratios range from 0.707489 to 0.711279;after correction,the^(87)Sr/^(86)Sr 145 Ma ratios range from 0.704721 to 0.707611,equivalent with the 87Sr/86Sr ratios of seawater at 145 Ma,indicating a marine origin.The decay of 87Rb in the evaporite during deposition,change of the depositional environment and the unsealed environment at a later period resulted in the present^(87)Sr/^(86)Sr ratios of some samples being high.The δ^(37)Cl value compositions range from−0.38‰to 0.83‰,which is consistent with the δ^(37)Cl value composition of the world marine halite(−0.6‰to 0.4‰),further confirming that seawater is the main origin.In addition,the high δ^(37)Cl value of some samples at the boundary of the upper and lower evaporite layers might be related to the influence of δ^(37)Cl-rich brine and the incomplete dissolution of the halite.
