The state of Tb3+ is investigated in liposome. When the concentration of PC is below CMC (critical micell concentration), most of Tb3+ is associated with PC, the binding constant is about 3.35×103 L/mol. When the...The state of Tb3+ is investigated in liposome. When the concentration of PC is below CMC (critical micell concentration), most of Tb3+ is associated with PC, the binding constant is about 3.35×103 L/mol. When the concentration of PC is beyond CMC, most of Tb3+ is dimerized, the dimerization constant is about 3.92×104L/mol. In PC?CH?H2O system, the binding constant of Tb3+?CH complex 2.93×104L/mol is obtained.展开更多
The molten liquid discrete flow inside a packed bed is a typical transport phenomenon in the blast furnace. As for the reported mathematical models presenting the liquid discrete flow within the packed bed, there are ...The molten liquid discrete flow inside a packed bed is a typical transport phenomenon in the blast furnace. As for the reported mathematical models presenting the liquid discrete flow within the packed bed, there are some barriers for their application to an engineering scale-up, or some imperfections in model descriptions. To overcome these deficiencies, the effects of the packed bed on the liquid discrete flow have been divided into resistance action and dispersal action, and appropriate descriptions have been given for the two aetions, respectively. Consequently, a new mathematical model has been built to present the liquid discrete flow inside a coke bed in the blast furnace. The mathematical model can predict the distribution of liquid flux and the liquid flowing range inside the packed bed at any time. The prediction of this model accords well with the experimental data. The model will be much better for the simulation of the ironmaking process, compared with the existent model.展开更多
文摘The state of Tb3+ is investigated in liposome. When the concentration of PC is below CMC (critical micell concentration), most of Tb3+ is associated with PC, the binding constant is about 3.35×103 L/mol. When the concentration of PC is beyond CMC, most of Tb3+ is dimerized, the dimerization constant is about 3.92×104L/mol. In PC?CH?H2O system, the binding constant of Tb3+?CH complex 2.93×104L/mol is obtained.
基金Item Sponsored by National Natural Science Foundation of China(50704040)
文摘The molten liquid discrete flow inside a packed bed is a typical transport phenomenon in the blast furnace. As for the reported mathematical models presenting the liquid discrete flow within the packed bed, there are some barriers for their application to an engineering scale-up, or some imperfections in model descriptions. To overcome these deficiencies, the effects of the packed bed on the liquid discrete flow have been divided into resistance action and dispersal action, and appropriate descriptions have been given for the two aetions, respectively. Consequently, a new mathematical model has been built to present the liquid discrete flow inside a coke bed in the blast furnace. The mathematical model can predict the distribution of liquid flux and the liquid flowing range inside the packed bed at any time. The prediction of this model accords well with the experimental data. The model will be much better for the simulation of the ironmaking process, compared with the existent model.
