[Objective]The paper was to guide scientific and rational use of emamectin benzoate in ginger.[Method]A field experiment was conducted to determine residue and degradation dynamics and final residue of emamectin benzo...[Objective]The paper was to guide scientific and rational use of emamectin benzoate in ginger.[Method]A field experiment was conducted to determine residue and degradation dynamics and final residue of emamectin benzoate in ginger.The residue of emamectin benzoate in ginger was determined by high performance liquid chromatography-mass spectrometry(HPLC-MS/MS).[Result]The half-life of emamectin benzoate in ginger was 2.2-3.4 d.As 5%emamectin benzoate WDG was sprayed on ginger at 7.5 and 11.25 g·a.i/hm^2 for consecutive 1-2 times,the residues of emamectin benzoate in ginger harvested at 7,14 and 21 d post spraying were lower than the quantitative limit of the method(0.01 mg/kg),and were lower than the stipulation in Japan as well(0.1 mg/kg).[Conclusion]It is safe to use emamectin benzoate in ginger with the harvest interval of 7 d according to the recommended dose.展开更多
建立液相色谱质谱联用快速检测菜薹中丙溴磷残留的分析方法,并对丙溴磷在菜薹中的残留消解及对人体的膳食摄入风险进行了研究。结果表明:丙溴磷在菜薹中半衰期为1.3~4.7 d。40%丙溴磷乳油,按照360 g a.i./hm^2和450 g a.i./hm^2用量,喷...建立液相色谱质谱联用快速检测菜薹中丙溴磷残留的分析方法,并对丙溴磷在菜薹中的残留消解及对人体的膳食摄入风险进行了研究。结果表明:丙溴磷在菜薹中半衰期为1.3~4.7 d。40%丙溴磷乳油,按照360 g a.i./hm^2和450 g a.i./hm^2用量,喷雾施药2~3次,施药间隔7 d,距末次施药后间隔5 d采样,菜薹中丙溴磷的残留中值为1.69 mg/kg。膳食风险评估结果表明:丙溴磷在所有登记作物中的总膳食摄入风险商(RQ)为0.30。膳食风险在可接受范围,说明丙溴磷在菜薹中残留不会对国人健康产生影响。展开更多
为评价虫螨腈在姜中使用的安全性,开展虫螨腈在姜中的残留量及残留降解研究。进行1年4地田间试验。消解动态试验按360g a.i/ha施药;最终残留试验按72g a.i/ha和108 g a.i/ha施药,施药1~2次,施药间隔7d,施药后7、14、21d采样姜样品。气...为评价虫螨腈在姜中使用的安全性,开展虫螨腈在姜中的残留量及残留降解研究。进行1年4地田间试验。消解动态试验按360g a.i/ha施药;最终残留试验按72g a.i/ha和108 g a.i/ha施药,施药1~2次,施药间隔7d,施药后7、14、21d采样姜样品。气相色谱对虫螨腈进行定量分析。田间消解动态试验表明:虫螨腈在植株中消解较快,在山东和安徽半衰期分别为6.0、8.2d。最终21d姜样品中虫螨腈的残留量在低于0.01~0.0495mg/kg,低于欧盟和日本制定的虫螨腈在姜中最大残留限量(0.05mg/kg)。展开更多
基金Supported by Agricultural Science and Technology Innovation Project of Shandong Academy of Agricultural Sciences(CXGC2018E19)
文摘[Objective]The paper was to guide scientific and rational use of emamectin benzoate in ginger.[Method]A field experiment was conducted to determine residue and degradation dynamics and final residue of emamectin benzoate in ginger.The residue of emamectin benzoate in ginger was determined by high performance liquid chromatography-mass spectrometry(HPLC-MS/MS).[Result]The half-life of emamectin benzoate in ginger was 2.2-3.4 d.As 5%emamectin benzoate WDG was sprayed on ginger at 7.5 and 11.25 g·a.i/hm^2 for consecutive 1-2 times,the residues of emamectin benzoate in ginger harvested at 7,14 and 21 d post spraying were lower than the quantitative limit of the method(0.01 mg/kg),and were lower than the stipulation in Japan as well(0.1 mg/kg).[Conclusion]It is safe to use emamectin benzoate in ginger with the harvest interval of 7 d according to the recommended dose.
文摘建立液相色谱质谱联用快速检测菜薹中丙溴磷残留的分析方法,并对丙溴磷在菜薹中的残留消解及对人体的膳食摄入风险进行了研究。结果表明:丙溴磷在菜薹中半衰期为1.3~4.7 d。40%丙溴磷乳油,按照360 g a.i./hm^2和450 g a.i./hm^2用量,喷雾施药2~3次,施药间隔7 d,距末次施药后间隔5 d采样,菜薹中丙溴磷的残留中值为1.69 mg/kg。膳食风险评估结果表明:丙溴磷在所有登记作物中的总膳食摄入风险商(RQ)为0.30。膳食风险在可接受范围,说明丙溴磷在菜薹中残留不会对国人健康产生影响。
文摘为评价虫螨腈在姜中使用的安全性,开展虫螨腈在姜中的残留量及残留降解研究。进行1年4地田间试验。消解动态试验按360g a.i/ha施药;最终残留试验按72g a.i/ha和108 g a.i/ha施药,施药1~2次,施药间隔7d,施药后7、14、21d采样姜样品。气相色谱对虫螨腈进行定量分析。田间消解动态试验表明:虫螨腈在植株中消解较快,在山东和安徽半衰期分别为6.0、8.2d。最终21d姜样品中虫螨腈的残留量在低于0.01~0.0495mg/kg,低于欧盟和日本制定的虫螨腈在姜中最大残留限量(0.05mg/kg)。
