The reaction of Ru (DMSO)_4Cl_2 with Dipheny1-[(pyrid-2-y1 ) amino]phosphine (pap) (1:2) gives the title compound Ru(PAP)_2Cl_2· 4EtoH. The crystallographic data for C_(24)H_(54)C_(12)N_4O_4P_2Ru: monoclinic,spac...The reaction of Ru (DMSO)_4Cl_2 with Dipheny1-[(pyrid-2-y1 ) amino]phosphine (pap) (1:2) gives the title compound Ru(PAP)_2Cl_2· 4EtoH. The crystallographic data for C_(24)H_(54)C_(12)N_4O_4P_2Ru: monoclinic,space group C2/c .α= 20. 47 (1) . b = 15. 431(9), c=15. 958(8) A , β=16. 82(4)°, V=4509(9) A3 ̄, Z=4, M_r= 912. 85, D_c= 1. 35 g/cm ̄3,μ(MoKα) = 5. 71 cm ̄(-1), F(000) =1092, R= 0. 073 and R_w = 0. 081 for 1700 observed reflections. The Ru atom is coordinated by two P atoms, two N atoms and two Cl atoms, forming octahedral coordination geomery.展开更多
文摘The reaction of Ru (DMSO)_4Cl_2 with Dipheny1-[(pyrid-2-y1 ) amino]phosphine (pap) (1:2) gives the title compound Ru(PAP)_2Cl_2· 4EtoH. The crystallographic data for C_(24)H_(54)C_(12)N_4O_4P_2Ru: monoclinic,space group C2/c .α= 20. 47 (1) . b = 15. 431(9), c=15. 958(8) A , β=16. 82(4)°, V=4509(9) A3 ̄, Z=4, M_r= 912. 85, D_c= 1. 35 g/cm ̄3,μ(MoKα) = 5. 71 cm ̄(-1), F(000) =1092, R= 0. 073 and R_w = 0. 081 for 1700 observed reflections. The Ru atom is coordinated by two P atoms, two N atoms and two Cl atoms, forming octahedral coordination geomery.