Bu_(3)SnH-and TMS_(3)SiH-assisted cyclizations of iodoarene derivatives of benzo[e][1,2,4]triazine lead to the formation of planar Blatter radicals(2-phenyl-3H-[1,2,4]triazino[5,6,1-kl]phenoxazin-3-yls and 2-phenyl-3H...Bu_(3)SnH-and TMS_(3)SiH-assisted cyclizations of iodoarene derivatives of benzo[e][1,2,4]triazine lead to the formation of planar Blatter radicals(2-phenyl-3H-[1,2,4]triazino[5,6,1-kl]phenoxazin-3-yls and 2-phenyl-3H-[1,2,4]triazino[5,6,1-kl]phenothiazin-3-yls)in yields of up to 96%.展开更多
基金Support for this work was provided by the National Science Center(2019/03/X/ST4/02006 and 2017/25/B/ST5/02851)。
文摘Bu_(3)SnH-and TMS_(3)SiH-assisted cyclizations of iodoarene derivatives of benzo[e][1,2,4]triazine lead to the formation of planar Blatter radicals(2-phenyl-3H-[1,2,4]triazino[5,6,1-kl]phenoxazin-3-yls and 2-phenyl-3H-[1,2,4]triazino[5,6,1-kl]phenothiazin-3-yls)in yields of up to 96%.