While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is curr...While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.展开更多
Recent years have seen notable progress in the use of deep eutectic solvents(DESs)in pharmaceutical applications.This is ascribed to the high preparation flexibility of DES mixtures and the ability tomulti-tune their ...Recent years have seen notable progress in the use of deep eutectic solvents(DESs)in pharmaceutical applications.This is ascribed to the high preparation flexibility of DES mixtures and the ability tomulti-tune their physicochemical properties and biopharmaceutical characteristics.The aim of this article is to provide perspective concerning the applications of DESs in pharmaceutical systems and their potential based on the current state of the field.Notably,there is some disagreement about whether some mixtures are in fact DESs or ionic liquids(ILs)[1].This indicates the need for more robust standards and definitions so as to avoid confusion within the scientific community.Many studies consider DESs to either constitute a subclass of ILs,analogs of ILs,or alternatives to ILs.In this regard,it would be best for the IUPAC to standardize DES classification and their similarity/dissimilarity with ILs.展开更多
基金the Ministry of Higher Education,Research and Innovation(MoHERI)Oman for their support of this research through TRC block funding Grant no.:BFP/RGP/EBR/22/378。
文摘While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.
文摘Recent years have seen notable progress in the use of deep eutectic solvents(DESs)in pharmaceutical applications.This is ascribed to the high preparation flexibility of DES mixtures and the ability tomulti-tune their physicochemical properties and biopharmaceutical characteristics.The aim of this article is to provide perspective concerning the applications of DESs in pharmaceutical systems and their potential based on the current state of the field.Notably,there is some disagreement about whether some mixtures are in fact DESs or ionic liquids(ILs)[1].This indicates the need for more robust standards and definitions so as to avoid confusion within the scientific community.Many studies consider DESs to either constitute a subclass of ILs,analogs of ILs,or alternatives to ILs.In this regard,it would be best for the IUPAC to standardize DES classification and their similarity/dissimilarity with ILs.
