Cubic phase Tm^(3+)/Yb^(3+):Y_(2)O_(3) and Tm^(3+)/Yb^(3+)/Gd^(3+):Y_(2)O_(3) phosphors were prepared by low temperature combustion technique for upconversion emission in UV-visible range.The 980 nm excitation has gen...Cubic phase Tm^(3+)/Yb^(3+):Y_(2)O_(3) and Tm^(3+)/Yb^(3+)/Gd^(3+):Y_(2)O_(3) phosphors were prepared by low temperature combustion technique for upconversion emission in UV-visible range.The 980 nm excitation has generated UV emission at 314 nm in tridoped phosphor due to the energy transfer from Tm^(3+) to Gd^(3+)ion.Characteristic emission bands from Tm^(3+) are also observed in both the phosphors.Thermally coupled Stark sublevels ^(1)G_(4(a))(476 nm) and ^(1)G_(4(b))(488 nm) of Tm^(3+) ion were utilised for optical thermometry using fluorescent intensity ratio(FIR) method.The result shows that maximum absolute sensitivity in tridoped phosphor is observed to be 1.33 × 10^(-3) K^(-1) at 298 K.Moreover,temperature rise of phosphor at various pump power densities was also measured and it is estimated to achieve 407 K at the pump power density of 38.46 W/cm^(2).展开更多
基金supported by the DST-SERB,New Delhi,India (EMR/000228/2017)TEQIP-Ⅲ,Ministry of Education,Government of India。
文摘Cubic phase Tm^(3+)/Yb^(3+):Y_(2)O_(3) and Tm^(3+)/Yb^(3+)/Gd^(3+):Y_(2)O_(3) phosphors were prepared by low temperature combustion technique for upconversion emission in UV-visible range.The 980 nm excitation has generated UV emission at 314 nm in tridoped phosphor due to the energy transfer from Tm^(3+) to Gd^(3+)ion.Characteristic emission bands from Tm^(3+) are also observed in both the phosphors.Thermally coupled Stark sublevels ^(1)G_(4(a))(476 nm) and ^(1)G_(4(b))(488 nm) of Tm^(3+) ion were utilised for optical thermometry using fluorescent intensity ratio(FIR) method.The result shows that maximum absolute sensitivity in tridoped phosphor is observed to be 1.33 × 10^(-3) K^(-1) at 298 K.Moreover,temperature rise of phosphor at various pump power densities was also measured and it is estimated to achieve 407 K at the pump power density of 38.46 W/cm^(2).
