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采用氯铁(Ⅱ)络离子回收稀水溶液中Au的动力学分析(英文)
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作者 Marek WOJNICKI Krzysztof FITZNER magdalena luty-blocho 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第6期2027-2036,共10页
采用停流法研究氯铁(II)络离子还原氯金(III)络离子的动力学。研究氯金(III)络合离子、Fe2+离子、Cl-离子和中性盐(Na Cl O4)的初始浓度、溶液p H值和温度的影响。确定激活能为42.36 k J/mol。此外,提出了动力学方程。采用SEM对所得固... 采用停流法研究氯铁(II)络离子还原氯金(III)络离子的动力学。研究氯金(III)络合离子、Fe2+离子、Cl-离子和中性盐(Na Cl O4)的初始浓度、溶液p H值和温度的影响。确定激活能为42.36 k J/mol。此外,提出了动力学方程。采用SEM对所得固相进行分析。粒子直径为0.5~5μm。结果表明通过还原溶液中氯金(III)络离子并过滤沉淀可以得到Au。 展开更多
关键词 金回收 还原 回收 电子废料
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Electro-Oxidation of Glucose in Alkaline Media on Graphene Sheets Decorated with Gold Nanoparticles
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作者 Marek Wojnicki magdalena luty-blocho +4 位作者 Iwona Dobosz Justyna Grzonka Krzysztof Paclawski Krzysztof J.Kurzydlowski Krzysztof Fitzner 《Materials Sciences and Applications》 2013年第2期162-169,共8页
In this study the catalytic properties of gold nanoparticles in electro-oxidation process of glucose, were investigated, taking into account, an influence of catalyst composition. Graphene oxide was applied and for el... In this study the catalytic properties of gold nanoparticles in electro-oxidation process of glucose, were investigated, taking into account, an influence of catalyst composition. Graphene oxide was applied and for electro-oxidation studies of glucose, cyclic voltamperometry was used. It was found that an application of graphene oxide sheets during catalyst synthesis have an influence on gold nanoparticles (AuNPs) size and size distribution. It was confirmed that the application of composite catalyst consisting of graphane-AuNPs significantly changes electro-oxidation of glucose shifting the potential of oxidation to higher positive values and increasing oxidation current. 展开更多
关键词 Glucose Oxidation Gold Nanoparticles Graphene Oxide Mocroflow Reactor MICROREACTOR
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