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电化学介导胺再生CO_(2)捕集系统电化学性能研究 被引量:1
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作者 范会峰 吴小梅 +3 位作者 刘广鑫 maimoona sharif 余云松 张早校 《高校化学工程学报》 EI CAS CSCD 北大核心 2022年第2期235-241,共7页
二氧化碳(CO_(2))捕集是实现我国碳中和目标的重要手段。电化学介导胺再生(EMAR)CO_(2)捕集系统是一种极具应用前景的碳捕集技术。为了进一步研究EMAR的电化学性能,利用H型电解池,对以乙醇胺(MEA)溶液为吸收剂,铜离子为金属配体的体系... 二氧化碳(CO_(2))捕集是实现我国碳中和目标的重要手段。电化学介导胺再生(EMAR)CO_(2)捕集系统是一种极具应用前景的碳捕集技术。为了进一步研究EMAR的电化学性能,利用H型电解池,对以乙醇胺(MEA)溶液为吸收剂,铜离子为金属配体的体系开展电化学行为研究。结果表明:阴极和阳极反应均是分步进行的,且均由扩散和电荷传递共同控制,阴极过程更缓慢,是系统的控制步骤。同时,增大阴阳极之间配合物浓度差,在较低阳极配合物浓度和较高阴极配合物浓度的情况下,更有利于系统反应的进行。研究结果有望为EMAR CO_(2)捕集技术的放大研究和实际应用提供一定的理论支撑。 展开更多
关键词 二氧化碳捕集 电化学介导胺再生 H型电解池 电化学性能
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Resource utilization of solid waste carbide slag:a brief review of application technologies in various scenes 被引量:3
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作者 Hongxia Wang Wanyi Xu +2 位作者 maimoona sharif Guangxu Cheng Zaoxiao Zhang 《Waste Disposal and Sustainable Energy》 2022年第1期1-16,共16页
China is the largest producer and consumer of calcium carbide in the world.The calcium carbide industry is an indispensable industry to support the basic life of people.The huge production capacity of calcium carbide ... China is the largest producer and consumer of calcium carbide in the world.The calcium carbide industry is an indispensable industry to support the basic life of people.The huge production capacity of calcium carbide is accompanied by a large number of solid waste carbide slag.Due to the immature treatment technology of carbide slag,a large number of carbide slag are stacked on-site,resulting in land occupation,air-drying,easy take-off ash,and pollution of the environment and water resources.In China,calcium carbide is mainly used to produce acetylene and further utilized,80%of which is used to produce polyvinyl chloride(PVC).A large amount of carbide slag is not used,while only a small part is used in the traditional building materials industry,flue gas desulfurization,sewage treatment,etc.,however,the economic benefits are poor.Therefore,converting the solid waste carbide slag produced by the calcium carbide industry into high value-added CaCO3,CaCl2,CaSO4 whiskers,etc.has become a potential way to expand the development field of the calcium carbide industry and is environmentally friendly.This paper focuses on summarizing the traditional and emerging high value-added utiliza-tion technologies of carbide slag,and then introduces the application research of carbide slag in carbon emission reduction.Finally,the defects of these technologies are summarized and further research directions are prospected.This study provides basic guidance for the diversified development of efficient resource utilization of carbide slag.Graphical abstract Diversified development of calcium carbide industry,resource utilization of solid waste carbide slag and its application of carbon emission reduction have been fully reviewed. 展开更多
关键词 Calcium carbide Carbide slag Application research High added value Carbon emission reduction
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