Highly transparent and super-wettable nanocoatings for multifunctional applications with outstanding physical properties are in high demanded.However,such nanocoatings resistant to water invasion and Ultraviolet(UV)we...Highly transparent and super-wettable nanocoatings for multifunctional applications with outstanding physical properties are in high demanded.However,such nanocoatings resistant to water invasion and Ultraviolet(UV)weathering remain a significant challenge.In this work,physically durable coatings based on inorganic nanoparticles(NPs)and an organic segment(isocyanate-silane modified surfactant)have been synthesized via a sol-gel approach.It is noteworthy the isocyanate-silane with-NH-C=O-functional group creates a strong bonding between the highly hydrophilic surfactant and the inorganic NPs.This in-house synthesized organic segment can render the coating long-lasting wetting properties and resist to be washed away by water,while the inorganic NPs can form sturdy covalent bonds with the nano-scale hierarchical structure on the glazing substrate to improve the durability.This nanocoating demonstrates high transparency with superwetting property(water contact angle,WCA=4.4±0.3°),effective de-frosting performance.Water invasion or UV accelerated weathering tests do not significantly affect the self-cleaning performance of nanocoating.Physical properties,including coating adhesion,hardness,Young's modulus,and abrasion resistance are systematically investigated.Interestingly,this clear coating shows prominent infrared shielding property attributed to Antimony-doped tin oxide(Sb-doped SnO_(2))NPs.The developed nanocoating process is easy to scale up for larger areas that require multipurpose self-cleaning functions.展开更多
基金The Hong Kong University of Science and Technology(Grants#:R9365,F0776,and F0782).
文摘Highly transparent and super-wettable nanocoatings for multifunctional applications with outstanding physical properties are in high demanded.However,such nanocoatings resistant to water invasion and Ultraviolet(UV)weathering remain a significant challenge.In this work,physically durable coatings based on inorganic nanoparticles(NPs)and an organic segment(isocyanate-silane modified surfactant)have been synthesized via a sol-gel approach.It is noteworthy the isocyanate-silane with-NH-C=O-functional group creates a strong bonding between the highly hydrophilic surfactant and the inorganic NPs.This in-house synthesized organic segment can render the coating long-lasting wetting properties and resist to be washed away by water,while the inorganic NPs can form sturdy covalent bonds with the nano-scale hierarchical structure on the glazing substrate to improve the durability.This nanocoating demonstrates high transparency with superwetting property(water contact angle,WCA=4.4±0.3°),effective de-frosting performance.Water invasion or UV accelerated weathering tests do not significantly affect the self-cleaning performance of nanocoating.Physical properties,including coating adhesion,hardness,Young's modulus,and abrasion resistance are systematically investigated.Interestingly,this clear coating shows prominent infrared shielding property attributed to Antimony-doped tin oxide(Sb-doped SnO_(2))NPs.The developed nanocoating process is easy to scale up for larger areas that require multipurpose self-cleaning functions.
