Anisotropic CeCo4.325_xCuo.675Fex （x ： 0.475- 0.875） sintered magnets were prepared by traditional powder metallurgical method. Influence of ball-nfilling time and iron content on microstructure and magnetic proper...Anisotropic CeCo4.325_xCuo.675Fex （x ： 0.475- 0.875） sintered magnets were prepared by traditional powder metallurgical method. Influence of ball-nfilling time and iron content on microstructure and magnetic properties of the CeCo4,325-xCuo.675Fex sintered magnets were investigated. It is shown that the properties of the magnet produced by mag- netic powders ball-milled for 40 min are better than that for 30 rain. With iron content increasing, remanence Br and maxi- mum energy product （BH）m increase first and then decrease. The optimal magnetic properties are obtained for the CeCo3.65Cuo.675Feo.675 sintered magnet： Br=0.685 T, the intrinsic coercivity Hci = 350 kA.m-1, and （BH）m ： 85.6 kJ.m-3. The increase of Br is mainly influenced by iron content of 1：5 matrix which can properly increase the saturation induction Bs; the rapid increase of the amount of Ce-rich phase and 5：19 phase gives rise to the deterioration of the magnets when x ≥ 0.775.展开更多
基金financially supported by the National High-Tech R&D Program of China(No.2010AA03A401)the National Basic Research Program of China(No.2010CB934601)the National Nature Science Foundation of China(Nos.50931001and 51241009)
文摘Anisotropic CeCo4.325_xCuo.675Fex （x ： 0.475- 0.875） sintered magnets were prepared by traditional powder metallurgical method. Influence of ball-nfilling time and iron content on microstructure and magnetic properties of the CeCo4,325-xCuo.675Fex sintered magnets were investigated. It is shown that the properties of the magnet produced by mag- netic powders ball-milled for 40 min are better than that for 30 rain. With iron content increasing, remanence Br and maxi- mum energy product （BH）m increase first and then decrease. The optimal magnetic properties are obtained for the CeCo3.65Cuo.675Feo.675 sintered magnet： Br=0.685 T, the intrinsic coercivity Hci = 350 kA.m-1, and （BH）m ： 85.6 kJ.m-3. The increase of Br is mainly influenced by iron content of 1：5 matrix which can properly increase the saturation induction Bs; the rapid increase of the amount of Ce-rich phase and 5：19 phase gives rise to the deterioration of the magnets when x ≥ 0.775.
