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Road-safety recognition and network equilibrium with perceived route-choice sets 被引量:2
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作者 mao-sheng li He-lai Huang 《Transportation Safety and Environment》 EI 2019年第2期126-134,共9页
Safety is regarded as the second basic need in Maslow’s hierarchy of needs(1943),and safety recognition and circumvention behaviour in the route-choice decision-making process should therefore be accommodated in netw... Safety is regarded as the second basic need in Maslow’s hierarchy of needs(1943),and safety recognition and circumvention behaviour in the route-choice decision-making process should therefore be accommodated in network-traffic equilibrium analysis frameworks.This paper proposes a framework by which crash frequency,forecasted using the safety-analysis method or compiled from historical data for intersections,is used to measure the safety consciousness of drivers.Drivers are then classified into different groups according to their acceptable-risk thresholds,and each group has its own route-choice set.Decision behaviour whereby drivers are willing to bear additional costs in order to circumvent travel risk is incorporated into the variational inequality model based on the user equilibrium in the perceived route-choice set(UE-PRCS),which is an extension of Wardrop’s first principle.The Frank–Wolfe algorithm,based on the convex combination method,is employed to obtain the solution.A small road network is used as a case study to illustrate the proposed framework,incorporating risk recognition and circumvention behaviour under different combinations of traffic demand and risk-sensitivity group ratio.The results show that the standard user equilibrium is a special case of the UE-PRCS,but that the UE traffic state is more common than the UE-PRCS under different parameters. 展开更多
关键词 safety recognition risk circumvention network-equilibrium analysis perceived route-choice set
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Lewis酸碱对催化的可再生环状缩醛酯单体的开环聚合研究
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作者 汤家栋 李茂盛 陶友华 《高分子学报》 SCIE CAS CSCD 北大核心 2023年第3期356-364,共9页
从生物质原料3,4-二氢吡喃出发,合成了可再生环状缩醛酯单体(H-AE),从结构上看,该单体在γ-丁内酯中引入了缩醛单元,在开环聚合过程中,通过释放甲醛分子有希望在温和条件下得到聚(γ-丁内酯).选用合适的Lewis酸碱对催化剂,基本抑制了聚... 从生物质原料3,4-二氢吡喃出发,合成了可再生环状缩醛酯单体(H-AE),从结构上看,该单体在γ-丁内酯中引入了缩醛单元,在开环聚合过程中,通过释放甲醛分子有希望在温和条件下得到聚(γ-丁内酯).选用合适的Lewis酸碱对催化剂,基本抑制了聚合过程中的链回咬副反应,实现了单体的可控聚合.详细研究了催化剂的酸/碱性强度及其位阻大小对于合成的聚合物的组成和比例的影响,通过设计和优化催化剂的结构,实现了聚合物中聚丁内酯单元和聚缩醛酯单元比例的调控.对所得聚合物进行了1H-NMR、13C-NMR及扩散排序核磁共振(DOSY)表征,结合聚合过程的核磁与SEC监测,证实所得聚合物为丁内酯与缩醛酯的无规共聚物.根据实验数据和表征结果,推测聚合遵循Lewis酸碱对调控的阴离子开环聚合机理,酸碱催化剂共同稳定活性链末端,实现了亲核进攻和甲醛的脱除. 展开更多
关键词 开环聚合 Lewis酸碱对 环状缩醛酯 聚(γ-丁内酯)
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Twist-teleportation-based local discrimination of maximally entangled states 被引量:1
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作者 mao-sheng li Shao-Ming Fei +1 位作者 Zong-Xing Xiong Yan-ling Wang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2020年第8期46-52,共7页
In this work,we study the local distinguishability of maximally entangled states(MESs).In particular,we are concerned with whether any fixed number of MESs can be locally distinguishable for sufficiently large dimensi... In this work,we study the local distinguishability of maximally entangled states(MESs).In particular,we are concerned with whether any fixed number of MESs can be locally distinguishable for sufficiently large dimensions.Fan and Tian et al.have already obtained two satisfactory results for the generalized Bell states(GBSs)and the qudit lattice states when applied to prime or prime power dimensions.We construct a general twist-teleportation scheme for any orthonormal basis with MESs that is inspired by the method used in[Phys.Rev.A 70,022304(2004)].Using this teleportation scheme,we obtain a sufficient and necessary condition for one-way distinguishable sets of MESs,which include the GBSs and the qudit lattice states as special cases.Moreover,we present a generalized version of the results in[Phys.Rev.A 92,042320(2015)]for the arbitrary dimensional case. 展开更多
关键词 TELEPORTATION local discrimination maximally entangled states
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