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Selected Chemical Aspects of Nuclear Power Development
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作者 Andrzej G. Chmielewski marcin brykala Tomasz Smolinski 《World Journal of Nuclear Science and Technology》 2012年第4期154-160,共7页
The Fukushima nuclear power plant (NPP) accident consequences are a new challenge for nuclear power development;however the sequence of the event has illustrated importance of radiation- and radiochemistry processes o... The Fukushima nuclear power plant (NPP) accident consequences are a new challenge for nuclear power development;however the sequence of the event has illustrated importance of radiation- and radiochemistry processes on the safe operation and shut down of nuclear reactor and decontamination of formed liquid and solid wastes. A chemistry program is essential for the safe operation of a nuclear power plant. It ensures the integrity, reliability and availability of the main plant structures, systems and components important to safety, in accordance with the assumptions and intent of the design. The proper implementation of these procedures minimizes the harmful effects of chemical impurities and corrosion on plant structures, systems and components. It supports the minimization of buildup of radioactive material and occupational radiation exposure as well as limiting of the release of chemicals and radioactive material to the en- vironment [1]. 展开更多
关键词 CHEMISTRY NUCLEAR Safety Water RADIOLYSIS RADIOACTIVE WASTE Treatment
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Sol-Gel Processing of Silica Nuclear Waste Glasses
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作者 Andrzej Deptula Magdalena Milkowska +7 位作者 Wieslawa Lada Tadeusz Olczak Danuta Wawszczak Tomasz Smolinski Fabio Zaza marcin brykala Andrzej G.Chmielewski Kenneth C.Goretta 《New Journal of Glass and Ceramics》 2011年第3期105-111,共7页
A complex Sol-Gel process has been used for synthesis of silica glasses designed to contain high-level nuclear wastes. Cs, Sr, Co, and Nd (generically denoted Me) were used, the last as surrogate for actinides. Gels i... A complex Sol-Gel process has been used for synthesis of silica glasses designed to contain high-level nuclear wastes. Cs, Sr, Co, and Nd (generically denoted Me) were used, the last as surrogate for actinides. Gels in the form of powders and sintered compacts were prepared by hydrolysis and polycondensation of tetraethoxide/Me nitrate solutions, which contained ascorbic acid as a catalyst. Thermal treatment studies were conducted on the resulting gels. Transformation to final products was studied by thermogravimetric analysis, infrared spectroscopy, and X-ray diffraction. Preliminary testing of Me leaching was also completed in quiescent water. Only a single dense form was resistant to 展开更多
关键词 SOL-GEL Silica Glass Nuclear Waste Thermal Treatment
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