The kinetics of Au3＋ chloride complex ions reduction using Fe2＋ chloride ions was investigated by stopped-flow method. The influence of initial concentrations of Au3＋ chloride ions, Fe2＋ ions, chloride ions, neutr...The kinetics of Au3＋ chloride complex ions reduction using Fe2＋ chloride ions was investigated by stopped-flow method. The influence of initial concentrations of Au3＋ chloride ions, Fe2＋ ions, chloride ions, neutral salt （NaC104）, pH of the solution and temperature was investigated. Activation energy was determined to be 42.36 kJ/mol. Moreover, the kinetic equation was postulated. Obtained solid phase was analyzed using SEM techniques. Particles size varies in the range from 0.5 to 5 gm. It was shown that gold can be removed from the solution by the reduction ofAu3＋ chloride ions and filtration of precipitant.展开更多
In this study the catalytic properties of gold nanoparticles in electro-oxidation process of glucose, were investigated, taking into account, an influence of catalyst composition. Graphene oxide was applied and for el...In this study the catalytic properties of gold nanoparticles in electro-oxidation process of glucose, were investigated, taking into account, an influence of catalyst composition. Graphene oxide was applied and for electro-oxidation studies of glucose, cyclic voltamperometry was used. It was found that an application of graphene oxide sheets during catalyst synthesis have an influence on gold nanoparticles (AuNPs) size and size distribution. It was confirmed that the application of composite catalyst consisting of graphane-AuNPs significantly changes electro-oxidation of glucose shifting the potential of oxidation to higher positive values and increasing oxidation current.展开更多
基金supported by the European Grant No.POIG.01.01.02.-00-015/09-00
文摘The kinetics of Au3＋ chloride complex ions reduction using Fe2＋ chloride ions was investigated by stopped-flow method. The influence of initial concentrations of Au3＋ chloride ions, Fe2＋ ions, chloride ions, neutral salt （NaC104）, pH of the solution and temperature was investigated. Activation energy was determined to be 42.36 kJ/mol. Moreover, the kinetic equation was postulated. Obtained solid phase was analyzed using SEM techniques. Particles size varies in the range from 0.5 to 5 gm. It was shown that gold can be removed from the solution by the reduction ofAu3＋ chloride ions and filtration of precipitant.
基金The authors gratefully acknowledge for financial support from AGH University of Science and Technology(con-tract No.11.11.180.373.2011)and European Grant No.POIG.01.01.02.-00-015/09-00.
文摘In this study the catalytic properties of gold nanoparticles in electro-oxidation process of glucose, were investigated, taking into account, an influence of catalyst composition. Graphene oxide was applied and for electro-oxidation studies of glucose, cyclic voltamperometry was used. It was found that an application of graphene oxide sheets during catalyst synthesis have an influence on gold nanoparticles (AuNPs) size and size distribution. It was confirmed that the application of composite catalyst consisting of graphane-AuNPs significantly changes electro-oxidation of glucose shifting the potential of oxidation to higher positive values and increasing oxidation current.
