In this study,the composition of tars collected during a six-day underground coal gasification(UCG)test at the experimental mine‘Barbara’in Poland in 2013 was examined.During the test,tar samples were taken every da...In this study,the composition of tars collected during a six-day underground coal gasification(UCG)test at the experimental mine‘Barbara’in Poland in 2013 was examined.During the test,tar samples were taken every day from the liquid product separator and analysed by the methods used for testing properties of typical coke oven(coal)tar.The obtained results were compared with each other and with the data for coal tar.As gasification progressed,a decreasing trend in the water content and an increasing trend in the ash content were observed.The tars tested were characterized by large changes in the residue after coking and content of parts insoluble in toluene and by smaller fluctuations in the content of parts insoluble in quinoline.All tested samples were characterized by very high distillation losses,while for samples starting from the third day of gasification,a clear decrease in losses was visible.A chromatographic analysis showed that there were no major differences in composition between the tested tars and that none of the tar had a dominant component such as naphthalene in coal tar.The content of polycyclic aromatic hydrocarbons(PAHs)in UCG tars is several times lower than that in coal tar.No light monoaromatic hydrocarbons(benzene,toluene,ethylbenzene and xylenes—BTEX)were found in the analysed tars,which results from the fact that these compounds,due to their high volatility,did not separate from the process gas in the liquid product separator.展开更多
A 72-h ex situ hard coal gasification test in one large block of coal was carried out.The gasifying agent was oxygen with a constant flow rate of 4.5 m^(3)/h.The surroundings of coal were simulated with wet sand with ...A 72-h ex situ hard coal gasification test in one large block of coal was carried out.The gasifying agent was oxygen with a constant flow rate of 4.5 m^(3)/h.The surroundings of coal were simulated with wet sand with 11%moisture content.A 2-cm interlayer of siderite was placed in the horizontal cut of the coal block.As a result of this process,gas with an average flow rate of 12.46 m^(3)/h was produced.No direct influence of siderite on the gasification process was observed;however,measurements of CO_(2)content in the siderite interlayer before and after the process allow to determine the location of high-temperature zones in the reactor.The greatest influence on the efficiency of the gasification process was exerted by water contained in wet sand.At the high temperature that prevailed in the reactor,this water evaporated and reacted with the incandescent coal,producing hydrogen and carbon monoxide.This reaction contributes to the relatively high calorific value of the resulting process gas,averaging 9.41 MJ/kmol,and to the high energy efficiency of the whole gasification process,which amounts to approximately 70%.展开更多
基金This work was a part of the HUGE 2 project and was jointly supported by the Research Fund for Coal and Steel,under contract RFCR-CT-2011-00002 and by the Polish Ministry of Science and Higher Education.
文摘In this study,the composition of tars collected during a six-day underground coal gasification(UCG)test at the experimental mine‘Barbara’in Poland in 2013 was examined.During the test,tar samples were taken every day from the liquid product separator and analysed by the methods used for testing properties of typical coke oven(coal)tar.The obtained results were compared with each other and with the data for coal tar.As gasification progressed,a decreasing trend in the water content and an increasing trend in the ash content were observed.The tars tested were characterized by large changes in the residue after coking and content of parts insoluble in toluene and by smaller fluctuations in the content of parts insoluble in quinoline.All tested samples were characterized by very high distillation losses,while for samples starting from the third day of gasification,a clear decrease in losses was visible.A chromatographic analysis showed that there were no major differences in composition between the tested tars and that none of the tar had a dominant component such as naphthalene in coal tar.The content of polycyclic aromatic hydrocarbons(PAHs)in UCG tars is several times lower than that in coal tar.No light monoaromatic hydrocarbons(benzene,toluene,ethylbenzene and xylenes—BTEX)were found in the analysed tars,which results from the fact that these compounds,due to their high volatility,did not separate from the process gas in the liquid product separator.
基金The research presented in this article was performed within the work"Conducting an exsitu experiment of underground coal gasification with a mineral interlayer"commissioned and funded by the Silesian University of Technology in Gliwice,Department of Applied Geology,by order sign ZP/018521/18/ZZ/01987/18.
文摘A 72-h ex situ hard coal gasification test in one large block of coal was carried out.The gasifying agent was oxygen with a constant flow rate of 4.5 m^(3)/h.The surroundings of coal were simulated with wet sand with 11%moisture content.A 2-cm interlayer of siderite was placed in the horizontal cut of the coal block.As a result of this process,gas with an average flow rate of 12.46 m^(3)/h was produced.No direct influence of siderite on the gasification process was observed;however,measurements of CO_(2)content in the siderite interlayer before and after the process allow to determine the location of high-temperature zones in the reactor.The greatest influence on the efficiency of the gasification process was exerted by water contained in wet sand.At the high temperature that prevailed in the reactor,this water evaporated and reacted with the incandescent coal,producing hydrogen and carbon monoxide.This reaction contributes to the relatively high calorific value of the resulting process gas,averaging 9.41 MJ/kmol,and to the high energy efficiency of the whole gasification process,which amounts to approximately 70%.
