The intercalation behavior of spiro-(1,1)-bipyrrolidinium cation(SBP+) into graphite electrode from spiro-(1,1)-bipyrrolidinium tetrafluoroborate-ethylene carbonate(SBPBF4-EC) solutions is investigated by conventional...The intercalation behavior of spiro-(1,1)-bipyrrolidinium cation(SBP+) into graphite electrode from spiro-(1,1)-bipyrrolidinium tetrafluoroborate-ethylene carbonate(SBPBF4-EC) solutions is investigated by conventional electrochemical tests and in situ X-ray diffraction measurements. Two kinds of graphite intercalation compounds(GICs) with discrete characteristic intercalated gallery heights(IGHs)(ca. 0.95 and0.75 nm) can be obtained with varying the salt concentration. The effect of graphite type is also addressed.展开更多
基金financially supported by National Natural Science Foundation of China (No. 21975251)。
文摘The intercalation behavior of spiro-(1,1)-bipyrrolidinium cation(SBP+) into graphite electrode from spiro-(1,1)-bipyrrolidinium tetrafluoroborate-ethylene carbonate(SBPBF4-EC) solutions is investigated by conventional electrochemical tests and in situ X-ray diffraction measurements. Two kinds of graphite intercalation compounds(GICs) with discrete characteristic intercalated gallery heights(IGHs)(ca. 0.95 and0.75 nm) can be obtained with varying the salt concentration. The effect of graphite type is also addressed.
