We study collective diffusion coefficient (Dc) of Water-in-oil nanoemulsions (L2 phase) stabilized by AOT and dispersed in n-Decane oils by dynamic light scattering (DLS). At constant water concentration we vary the o...We study collective diffusion coefficient (Dc) of Water-in-oil nanoemulsions (L2 phase) stabilized by AOT and dispersed in n-Decane oils by dynamic light scattering (DLS). At constant water concentration we vary the oil concentration and there is clear evidence for a changing collective diffusion coefficient of the droplets in AOT nanoemuslion. The collective diffusion coefficient in AOT nanoemulsions is studied from relaxation investigations with dynamic light scattering. Also, we study the collective diffusion coefficient (Dc) of droplets with add the TBAC to the droplets of AOT nanoemulsion. We discuss the results with study structural investigations with small-angle x-ray scattering. The results of this study suggest that the formation of non-spherical aggregates at low concentration of droplets can describe the behavior of the collective diffusion coefficient at AOT nanoemulsion.展开更多
The mixture of C12E5 microemulsion with PEG have been studied by small-angle X-ray scattering and dynamic light scattering in order to determine structure and dynamic of the system. Light scattering experiment shown a...The mixture of C12E5 microemulsion with PEG have been studied by small-angle X-ray scattering and dynamic light scattering in order to determine structure and dynamic of the system. Light scattering experiment shown an exponential relaxation for pure C12E5 microemulsion that with increasing of PEG concentration in the C12E5 microemulsion, relaxation becomes non-exponential, which demonstrates that increase of cooperativity. The study structure of the system with SAXS experiment, shown with increasing of PEG concentration, the size of the droplet doesn’t change but interaction between droplets increases that have agreement with light scattering data’s.展开更多
he photon correlation spectroscopy and small-angle X-ray scattering is used for study the mixture of C12E5 microemulsion with PEG in order to determine structure and dynamic of the system. Photon correlation spectrosc...he photon correlation spectroscopy and small-angle X-ray scattering is used for study the mixture of C12E5 microemulsion with PEG in order to determine structure and dynamic of the system. Photon correlation spectroscopy experiment showed an exponential relaxation for pure C12E5 microemulsion that come from Brownian motion of oil nano-droplets in water. The shape of the relaxation changed with increasing of PEG concentration in the C12E5 microemulsion, (relaxation becomes non-exponential with the increase of PEG), which demonstrates an increase of cooperatively in the C12E5 microemulsion. The SAXS experiment was used to study the structure of the system, and a model consists of a mixture of core-shell spheres with an Asakura-Oosawa interaction was applied to analyze data.展开更多
文摘We study collective diffusion coefficient (Dc) of Water-in-oil nanoemulsions (L2 phase) stabilized by AOT and dispersed in n-Decane oils by dynamic light scattering (DLS). At constant water concentration we vary the oil concentration and there is clear evidence for a changing collective diffusion coefficient of the droplets in AOT nanoemuslion. The collective diffusion coefficient in AOT nanoemulsions is studied from relaxation investigations with dynamic light scattering. Also, we study the collective diffusion coefficient (Dc) of droplets with add the TBAC to the droplets of AOT nanoemulsion. We discuss the results with study structural investigations with small-angle x-ray scattering. The results of this study suggest that the formation of non-spherical aggregates at low concentration of droplets can describe the behavior of the collective diffusion coefficient at AOT nanoemulsion.
文摘The mixture of C12E5 microemulsion with PEG have been studied by small-angle X-ray scattering and dynamic light scattering in order to determine structure and dynamic of the system. Light scattering experiment shown an exponential relaxation for pure C12E5 microemulsion that with increasing of PEG concentration in the C12E5 microemulsion, relaxation becomes non-exponential, which demonstrates that increase of cooperativity. The study structure of the system with SAXS experiment, shown with increasing of PEG concentration, the size of the droplet doesn’t change but interaction between droplets increases that have agreement with light scattering data’s.
基金This work was supported by the University of Sistan and Baluchestan and SFB-569(DFG)the Research Collabo-rative Center of the Institut für Experimentelle Physik,Universität Ulm.
文摘he photon correlation spectroscopy and small-angle X-ray scattering is used for study the mixture of C12E5 microemulsion with PEG in order to determine structure and dynamic of the system. Photon correlation spectroscopy experiment showed an exponential relaxation for pure C12E5 microemulsion that come from Brownian motion of oil nano-droplets in water. The shape of the relaxation changed with increasing of PEG concentration in the C12E5 microemulsion, (relaxation becomes non-exponential with the increase of PEG), which demonstrates an increase of cooperatively in the C12E5 microemulsion. The SAXS experiment was used to study the structure of the system, and a model consists of a mixture of core-shell spheres with an Asakura-Oosawa interaction was applied to analyze data.
