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A visible light-mediated three-component strategy based on the ring-opening of cyclic ethers with aryldiazoacetates and nucleophiles
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作者 mateus l.stivanin Rafael D.C.Gallo +2 位作者 Joao Paulo M.Spadeto Rodrigo A.Cormanich Igor D.Jurberg 《Organic Chemistry Frontiers》 SCIE EI 2022年第5期1321-1326,共6页
A blue light-promoted reaction between aryldiazoacetates and different nucleophiles has been developed in the presence of THF(and other cyclic ethers)as the solvent,allowing the incorporation of these three elements i... A blue light-promoted reaction between aryldiazoacetates and different nucleophiles has been developed in the presence of THF(and other cyclic ethers)as the solvent,allowing the incorporation of these three elements into a single product.Formally,this transformation represents an O–H insertion strategy of more complex alcohols into aryldiazoesters,without the need of pre-assembling them.The method is mild and efficient and proceeds in the absence of metals,generally at room temperature. 展开更多
关键词 temperature VISIBLE LIGHT
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