The selective hydrogenation reactions play a key role in industrial manufacture of fine chemicals,which mainly rely on noble metal catalysts.Herein,a noble-metal-free hybrid photosystem is established,in which boron c...The selective hydrogenation reactions play a key role in industrial manufacture of fine chemicals,which mainly rely on noble metal catalysts.Herein,a noble-metal-free hybrid photosystem is established,in which boron carbonitride(BCN)and nickel bis-diphosphine complex(NiP)catalyze cooperatively the semi-hydrogenation of alkynes with high efficiency and excellent selectivity(>99%)under mild reaction conditions.展开更多
基金supported by the National Natural Science Foundation of China(grant nos.22071026,21673040,21961142019,22032002,and U1905214)the National Key R&D Program of China(no.2018YFA0209301)the Chang Jiang Scholars Program of China(no.T2016147),and the 111 Project(no.D16008).
文摘The selective hydrogenation reactions play a key role in industrial manufacture of fine chemicals,which mainly rely on noble metal catalysts.Herein,a noble-metal-free hybrid photosystem is established,in which boron carbonitride(BCN)and nickel bis-diphosphine complex(NiP)catalyze cooperatively the semi-hydrogenation of alkynes with high efficiency and excellent selectivity(>99%)under mild reaction conditions.
