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有机硅季铵盐的合成及其在洗护领域中的应用
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作者 蔡国强 王琳 +3 位作者 张艳 何美林 张蕾 何一波 《日用化学工业(中英文)》 CAS 北大核心 2024年第7期812-820,共9页
利用N,N-二甲基十二烷基胺与不同分子量的端环氧聚醚硅油进行端环氧基开环反应,合成出不同硅氧链长的二甲基十二烷基有机硅季铵盐。通过FT-IR确定了有机硅季铵盐产物的合成结构;考察了不同分子量有机硅季铵盐与市场样以及纯棉织物经样... 利用N,N-二甲基十二烷基胺与不同分子量的端环氧聚醚硅油进行端环氧基开环反应,合成出不同硅氧链长的二甲基十二烷基有机硅季铵盐。通过FT-IR确定了有机硅季铵盐产物的合成结构;考察了不同分子量有机硅季铵盐与市场样以及纯棉织物经样品处理后的抑菌效果;考察了不同分子量有机硅季铵盐及其在柔顺剂体系中对织物表面Zeta电位的影响;考察了有机硅季铵盐在柔顺剂体系中的柔顺效果、在多元表面活性剂体系中的抗再沉积性能。结果表明,研制的有机硅季铵盐具有优良的抑菌效果,在低质量分数(0.1%)下即可达到大于99.9%的抑菌率。同时有机硅季铵盐能吸附到织物表面,改变织物表面Zeta电位,仅1%有机硅季铵盐即可使织物表面Zeta电位从负电位提升至正电位,提升效果明显优于市场样。所研制的有机硅季铵盐不仅能提升柔顺剂对织物的柔顺效果,还能在洗涤剂体系中提高织物对炭黑和黄泥土的抗再沉积作用。相比于聚酯纤维,有机硅季铵盐在纤维素纤维上具有更好的抗再沉积效果。 展开更多
关键词 有机硅季铵盐 抑菌 柔顺 抗再沉积
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Crustal vertical deformation of Amazon Basin derived from GPS and GRACE/GFO data over past two decades 被引量:1
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作者 Jun Fang meilin he +1 位作者 Wei Luan Jiashuang Jiao 《Geodesy and Geodynamics》 CSCD 2021年第6期441-450,共10页
In this study,the Gravity Recovery and Climate Experiment(GRACE)satellite observations,combining 71 continuous Global Positioning System(CGPS)data,are used to detect surface vertical loading deformation of the Amazon ... In this study,the Gravity Recovery and Climate Experiment(GRACE)satellite observations,combining 71 continuous Global Positioning System(CGPS)data,are used to detect surface vertical loading deformation of the Amazon Basin during 2002-2020.The results show that the maximal annual amplitude of the surface mass changes derived by GRACE is more than 80 cm in terms of the equivalent water height(EWH)in the Amazon Basin.Most part of Amazon experiences mass gain,especially the Amazon River,while there is little mass loss in the northern and eastern parts.Through the Pearson correlation analysis,the monthly de-trended time series of GPS-observed vertical deformation and GRACE-derived mass loading are in good agreement with an average correlation coefficient of about 0.75 throughout the Amazon region.The common seasonal signals of GPS vertical displacements and GRACE/GFO loading deformations are extracted using the stack averaging.The two kinds of common seasonal signals show a good consistency,and together indicate approximate 20 mm peak-to-peak seasonal amplitude.Strong annual variations are identified both in the monthly GPS and GRACE/GFO data by the wavelet analysis.However,the time-frequency spectrum of GPS has more signal details and more significant semi-annual variations than that of GRACE/GFO.These results may contribute to the understanding of secular crustal vertical deformation in the Amazon Basin. 展开更多
关键词 Amazon Basin GRACE/GFO GPS Pearson correlation analysis Loading deformation
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