Oil product pipelines have features such as transporting multiple materials, ever-changing operating conditions, and synchronism between the oil input plan and the oil offloading plan. In this paper, an optimal model ...Oil product pipelines have features such as transporting multiple materials, ever-changing operating conditions, and synchronism between the oil input plan and the oil offloading plan. In this paper, an optimal model was established for a single-source multi-distribution oil pro- duct pipeline, and scheduling plans were made based on supply. In the model, time node constraints, oil offloading plan constraints, and migration of batch constraints were taken into consideration. The minimum deviation between the demanded oil volumes and the actual offloading volumes was chosen as the objective function, and a linear programming model was established on the basis of known time nodes＇ sequence. The ant colony optimization algo- rithm and simplex method were used to solve the model. The model was applied to a real pipeline and it performed well.展开更多
Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO.(SO_(2))_(2) and thianthrenium salts via a distal heteroaryl migration process has been developed,which provides a new means of synthesizing a varie...Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO.(SO_(2))_(2) and thianthrenium salts via a distal heteroaryl migration process has been developed,which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds.These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions,followed by distal heteroaryl migration.This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.展开更多
A three-component reaction of 1,3-enynes and cyclobutanone oxime esters in the presence of aryl boronic acids or organozinc reagents via the photoredox/copper or photoredox/nickel catalysis has been established.This r...A three-component reaction of 1,3-enynes and cyclobutanone oxime esters in the presence of aryl boronic acids or organozinc reagents via the photoredox/copper or photoredox/nickel catalysis has been established.This redox-neutral 1,4-cyanoalkylarylation reaction has demonstrated mild condition,high catalytic reactivity and wide functional group compatibility,allowing access to a variety of functionalized tetra-substituted allene derivatives with high chemo-and regioselectivity.Moreover,using photocatalytic continuous flow technique to promote this process would result in increased yields(70%in flow vs.61%in batch),reduced reaction times(7 min in flow vs.6 h in batch),and easy scale-up(upgrade to gram scale),showcasing its potential as a synthetic platform.展开更多
基金part of the Program of"Study on the mechanism of complex heat and mass transfer during batch transport process in products pipelines"funded under the National Natural Science Foundation of China(grant number 51474228)
文摘Oil product pipelines have features such as transporting multiple materials, ever-changing operating conditions, and synchronism between the oil input plan and the oil offloading plan. In this paper, an optimal model was established for a single-source multi-distribution oil pro- duct pipeline, and scheduling plans were made based on supply. In the model, time node constraints, oil offloading plan constraints, and migration of batch constraints were taken into consideration. The minimum deviation between the demanded oil volumes and the actual offloading volumes was chosen as the objective function, and a linear programming model was established on the basis of known time nodes＇ sequence. The ant colony optimization algo- rithm and simplex method were used to solve the model. The model was applied to a real pipeline and it performed well.
基金the National Natural Science Foundation of China(Nos.21702103 and 21522604)the Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(No.XTD2203)+1 种基金the Natural Science Research Projects of Jiangsu Higher Education(No.19KJB150027)Jiangsu Funding Program for Excellent Postdoctoral Talent(No.2022ZB389).
文摘Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO.(SO_(2))_(2) and thianthrenium salts via a distal heteroaryl migration process has been developed,which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds.These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions,followed by distal heteroaryl migration.This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.
基金This work was supported by the National Natural Science Foundation of China(Nos.21702103,21522604)the Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture(No.XTD2203)the Natural Science Research Projects of Jiangsu Higher Education(No.19KJB150027).
文摘A three-component reaction of 1,3-enynes and cyclobutanone oxime esters in the presence of aryl boronic acids or organozinc reagents via the photoredox/copper or photoredox/nickel catalysis has been established.This redox-neutral 1,4-cyanoalkylarylation reaction has demonstrated mild condition,high catalytic reactivity and wide functional group compatibility,allowing access to a variety of functionalized tetra-substituted allene derivatives with high chemo-and regioselectivity.Moreover,using photocatalytic continuous flow technique to promote this process would result in increased yields(70%in flow vs.61%in batch),reduced reaction times(7 min in flow vs.6 h in batch),and easy scale-up(upgrade to gram scale),showcasing its potential as a synthetic platform.
