Carbon dots derived from Poria cocos polysaccharide as an effective“on-off”fluorescence sensor for chromium(Ⅵ)detection

Chromium is a harmful contaminant showing mutagenicity and carcinogenicity.Therefore,detection of chromium requires the development of low-cost and high-sensitivity sensors.Herein,blue-fluorescent carbon quantum dots were synthesized by one-step hydrothermal method from alkali-soluble Poria cocos polysaccharide,which is green source,cheap and easy to obtain,and has no pharmacological activity due to low water solubility.These carbon quantum dots exhibit good fluorescence stability,water solubility,anti-interference and low cytotoxicity,and can be specifically combined with the detection of Cr(Ⅵ)to form a non-fluorescent complex that causes fluorescence quenching,so they can be used as a label-free nanosensor.High-sensitivity detection of Cr(Ⅵ)was achieved through internal filtering and static quenching effects.The fluorescence quenching degree of carbon dots fluorescent probe showed a good linear relationship with Cr(Ⅵ)concentration in the range of 1-100μM.The linear equation was F;/F=0.9942+0.01472[Cr(Ⅵ)](R;=0.9922),and the detection limit can be as low as 0.25μM(S/N=3),which has been successfully applied to Cr(Ⅵ)detection in actual water samples herein.

Study on the evaluation method of diffuse radiation models——taking 5 typical cities in China as examples

Diffuse solar radiation models play an extremely important role in solar photothermal utilization,resource assess-ment and energy consumption simulation,etc.The accuracy of these diffuse solar radiation models usually need to be evaluated by various statistical parameters.Among these statistical parameters,the Global Performance In-dex(GPI)has been extensively employed in recent years because of its comprehensiveness and wide applicability.This paper takes five cities in China as representatives of 5 typical climate regions,and 12 solar scattered radia-tion models are fitted with the meteorological data of 5 cities.Based on the comparative analysis of the existing GPI calculation methods,this paper points out that there are some defects in the existing GPI,and modifies the existing GPI based on the comprehensive consideration of statistical parameters,normalization preprocessing of statistical parameters,unified evaluation direction of parameters,weight redistribution of statistical parameters,and adjustment of extreme coefficient.12 types of new GPI are established in this paper,and the performance of diffuse solar radiation models are compared based on these GPI.The rationality of GPI corrective measures is analyzed by means of the method reasonable index(MRI).The results show that the GPI calculation method(N10)which takes five corrective measures has the best performance,and the accuracy of the existing GPI can be improved by 13.33 to 65%.