Bio‐inspired nanostructured g-C_(3)N_(4)-based photocatalysts:A comprehensive review

As a new organic conjugated semiconductor,graphitic carbon nitride(g-C_(3)N_(4))is emerging as a fascinating material for various photocatalytic applications due to its adjustable electronic structure,outstanding thermal endurance,appealing chemical stability,low cost,and environmental friendliness.Nevertheless,unmodified bulk g-C_(3)N_(4) possesses some intrinsic limitations related to poor crystallinity,marginal visible-light harvesting,easy recombination of charge pairs,small surface area,and slow charge migration,which give rise to the low quantum efficiency of photocatalytic reactions.One efficient strategy to overcome these shortcomings is the manipulation of the microstructures of g-C_(3)N_(4).Other than the traditional structure control,mimicking the structures of creatures in nature to design and construct bio-inspired structures is a promising approach to improve the photocatalytic performance of g-C_(3)N_(4) and even g-C_(3)N_(4)-based systems.This review summarizes the recent advances of the traditional structure-control of g-C_(3)N_(4)-based systems,and bio-inspired synthesis of g-C_(3)N_(4)-based systems from two aspects of structural bionics and functional bionics.Furthermore,the fundamentals of bio-inspired design and fabrication of g-C_(3)N_(4)-based systems are introduced in detail.Additionally,the different theoretical calculations,diverse photocatalytic applications and various modification strategies of bio-inspired structured g-C_(3)N_(4)-based systems are recapped.We believe that this work will be a guiding star for future research in the new field of biomimetic photocatalysis.

Construction of high-efficiency CoS@Nb_(2)O_(5) heterojunctions accelerating charge transfer for boosting photocatalytic hydrogen evolution

The random movement and easy recombination of photoinduced charges lead to a low conversion efficiency for photocatalytic hydrogen evolution.The cocatalyst design is a promising route to address such problem through introducing an appropriate cocatalyst on the semiconductor photocatalysts to construct the high-efficiency heterojunctions.Herein,novel CoS/Nb_(2)O_(5) heterojunctions were constructed via in-situ loading CoS cocatalyst on the surface of Nb_(2)O_(5) nanosheets.Through the femtosecond-resolved transient absorption spectroscopy,the average lifetime of charge carriers for 10 wt% CoS/Nb_(2)O_(5)(159.6 ps)is drastically shortened by contrast with that of Nb_(2)O_(5)(5531.9 ps),strongly suggesting the rapid charge transfer from Nb_(2)O_(5) to CoS.The significantly improved charge-transfer capacity contributes to a high photocatalytic hydrogen evolution rate of 355µmol/h,up to 17.5 times compared with pristine Nb_(2)O_(5).This work would provide a new design platform in the construction of photocatalytic heterojunctions with high charge-transfer efficiency.