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Recent advances in quasi-2D superconductors via organic molecule intercalation
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作者 石孟竹 康宝蕾 +1 位作者 吴涛 陈仙辉 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第10期66-73,共8页
Superconductivity at the 2D limit shows emergent novel quantum phenomena, including anomalously enhanced H_(c2),quantum metallic states and quantum Griffiths singularity, which has attracted much attention in the fiel... Superconductivity at the 2D limit shows emergent novel quantum phenomena, including anomalously enhanced H_(c2),quantum metallic states and quantum Griffiths singularity, which has attracted much attention in the field of condensed matter physics. In this article, we focus on new advances in quasi-2D superconductors in the bulk phase using an organic molecular electrochemical intercalation method. The enhanced superconductivity and emergent pseudogap behavior in these quasi-2D superconductors are summarized with a further prospect. 展开更多
关键词 organic molecular intercalation two-dimensional superconductivity organic-inorganic hybrid materials
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混合溶剂调控插层FeSe基超导体的层间距
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作者 胡国兵 石孟竹 +6 位作者 孟凡保 江风云 高敏 钟钒 陈欢 郭景锋 罗习刚 《Science China Materials》 SCIE EI CAS CSCD 2024年第1期295-300,共6页
近年来,通过湿化学方法探索合成新型插层FeSe基超导体一直是凝聚态物理的研究热点之一.本文中,我们利用溶剂热离子交换技术成功合成出两种FeSe衍生物:c轴晶胞参数为9.93Å的Li_(0.34)Se_(0.05)(EG)_(0.14)-FeSe和c轴晶胞参数为13.85... 近年来,通过湿化学方法探索合成新型插层FeSe基超导体一直是凝聚态物理的研究热点之一.本文中,我们利用溶剂热离子交换技术成功合成出两种FeSe衍生物:c轴晶胞参数为9.93Å的Li_(0.34)Se_(0.05)(EG)_(0.14)-FeSe和c轴晶胞参数为13.85Å的Li_(0.21)Se_(0.05)(EG)_(0.26)FeSe.通过调整反应溶剂可以调控以上两种FeSe衍生物的层间距.磁化率和电阻率测试表明它们的超导转变温度(Tc)均为30 K左右,似乎与FeSe层层间距的大小无关.与原始FeSe单晶相比,X射线光电子能谱结果显示FeSe层Fe的价态降低,这表明Tc的提高可能是由于电子掺杂效应引起的.我们的研究为探索合成插层铁基超导体提供了有价值的参考,并为在超导领域探索新型插层材料提供了新的可能性. 展开更多
关键词 超导转变温度 凝聚态物理 X射线光电子能谱 铁基超导体 混合溶剂 离子交换技术 湿化学方法 反应溶剂
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Spin-flop transition and Zeeman effect of defect-localized bound states in the antiferromagnetic topological insulator MnBi_(2)Te_(4)
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作者 Guojian Qian mengzhu shi +6 位作者 Hui Chen shiyu Zhu Jiawei Hu Zihao Huang Yuan Huang Xian-Hui Chen Hong-Jun Gao 《Nano Research》 SCIE EI CSCD 2023年第1期1101-1106,共6页
The correlation of surface impurity states with the antiferromagnetic ground states is crucial for understanding the formation of the topological surface state in the antiferromagnetic topological insulators MnBi_(2)T... The correlation of surface impurity states with the antiferromagnetic ground states is crucial for understanding the formation of the topological surface state in the antiferromagnetic topological insulators MnBi_(2)Te_(4).By using low-temperature scanning tunneling microscopy and spectroscopy,we observed a localized bound state around the Mn-Bi antisite defect at the Teterminated surface of the antiferromagnetic topological insulator MnBi_(2)Te_(4).When applying a magnetic field perpendicular to the surface(Bz)from–1.5 to 3.0 T,the bound state shifts linearly to a lower energy with increasing Bz,which is attributed to the Zeeman effect.Remarkably,when applying a large range of Bz from–8.0 to 8.0 T,the magnetic field induced reorientation of surface magnetic moments results in an abrupt jump in the local density of states(LDOS),which is characterized by LDOSchange-ratio■quantitatively.Interestingly,two asymmetric critical field,–2.0 and 4.0 T determined by the two peaks in■are observed,which is consistent with simulated results according to a Mills-model,describing a surface spin flop transition(SSF).Our results provide a new flatform for studying the interplay between magnetic order and topological phases in magnetic topological materials. 展开更多
关键词 antiferromagnetic topological insulators MnBi_(2)Te_(4) scanning tunneling microscope Mills model surface spin flop transition
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Electrical transport properties of Fe Se single crystal under high magnetic field 被引量:6
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作者 HongHui Wang ZhaoHui Cheng +6 位作者 mengzhu shi DongHui Ma WeiZhuang Zhuo ChuanYing Xi Tao Wu JianJun Ying XianHui Chen 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2021年第8期85-90,共6页
Understanding the normal electronic state is crucial for unveiling the mechanism of unconventional superconductivity(SC). In this paper, by applying a magnetic field of up to 37T on FeSe single crystals, we could reve... Understanding the normal electronic state is crucial for unveiling the mechanism of unconventional superconductivity(SC). In this paper, by applying a magnetic field of up to 37T on FeSe single crystals, we could reveal the normal-state transport properties after SC was completely suppressed. The normal-state resistivity exhibited a Fermi liquid behavior at low temperatures. Large orbital magnetoresistance(MR) was observed in the nematic state with H//c, whereas MR was negligible with H//ab. The magnitude of the orbital MR showed an unusual reduction, and Kohler’s rule was severely violated below 10-25 K;these were attributable to spin fluctuations. The results indicated that spin fluctuations played a paramount role in the normalstate transport properties of FeSe albeit the Fermi liquid nature was at low temperature. 展开更多
关键词 spin fluctuations Kohler’s rule FeSe-based superconductivity
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一种新的过渡金属层状材料Na4Cu3TaAs4的结构和物理性质(英文)
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作者 孟凡保 石梦竹 +5 位作者 崔胜涛 彭坤岭 王乃舟 孙喆 应剑俊 陈仙辉 《Science China Materials》 SCIE EI CSCD 2020年第5期816-822,共7页
我们报道了一种新的过渡金属层状砷化物Na4Cu3TaAs4的合成、结构和物理性质.这种材料采用Ⅰ√2 m空间群,晶胞参数为a=5.9101(3)?,c=13.8867(12)?.这个材料的结构中包含两层Na,而Na夹在反氧化铅型(Cu/Ta)As层之间,类似于"111"... 我们报道了一种新的过渡金属层状砷化物Na4Cu3TaAs4的合成、结构和物理性质.这种材料采用Ⅰ√2 m空间群,晶胞参数为a=5.9101(3)?,c=13.8867(12)?.这个材料的结构中包含两层Na,而Na夹在反氧化铅型(Cu/Ta)As层之间,类似于"111"型铁基超导体NaFeAs.过渡金属位由75%的Cu和25%的Ta占据,Ta形成了明确的√2超结构.Cu和Ta分别为+1和+5价.角分辨光电子能谱测得的Na4Cu3TaAs4能带结构能够和DFT计算结果良好地吻合.角分辨光电子能谱和输运测量均表明该材料表现为金属行为,具有p型载流子.磁化率测量表明该材料表现为几乎不依赖温度的抗磁性.这种新材料扩展了含有反氧化铅型层的材料系统,并为进一步研究该材料系统提供了一个很好的平台. 展开更多
关键词 LAYERED ARSENIDE anti-PbO-type layer superstructure band structure physical properties
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