Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechan...Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechanisms,etc.Isomers are good platform to investigate the charge storage mechanisms and enhance the performance of batteries,which,however,have not been focused in batteries.Herein,two isomers are reported for batteries.As a result,the isomer tetrathiafulvalene(TTF)could store two monovalent anions reversibly,deriving an average discharge voltage of 1.05 V and a specific capacity of 220 mAh g−1 at a current density of 2 C.On the other hand,the other isomer tetrathianaphthalene could only reversibly store one monovalent anion and upon further oxidation,it would undergo an irreversible solid-state molecular rearrangement to TTF.The molecular rearrangement was confirmed by electrochemical performances,X-ray diffraction patterns,nuclear magnetic resonance spectra,and 1H detected heteronuclear multiple bond correlation spectra.These results suggested the small structural change could lead to a big difference in anion storage,and we hope this work will stimulate more attention to the structural design for boosting the performance of organic batteries.展开更多
In recent years, with the rapid development of urbanization in China, land acquisition work is particularly important. The division of expropriated area is the primary factor to be considered when evaluating the compr...In recent years, with the rapid development of urbanization in China, land acquisition work is particularly important. The division of expropriated area is the primary factor to be considered when evaluating the comprehensive land price of expropriated area. Reasonable division can help to improve the scientific and applicability of the comprehensive land price of the region. How to maximize the protection of farmers’ rights and interests by the division of land requisition is an urgent problem to be solved. Taking Gongcheng Yao Autonomous County as an example, this study adopted the multi-factor comprehensive evaluation method to evaluate the division of land requisition in this area, and carried out the corresponding spatial analysis and data processing based on GIS technology. Gongcheng Yao Autonomous County was divided into levy areas, and the Delphi method was used to screen the impact factors and determine the weight of the levy areas. Reasonable division of land requisition area can provide references for land requisition area, make it more scientific and reasonable, and protect the rights and interests of farmers.展开更多
The quality of cultivated land has an important influence on agricultural output, food security, sustainable development and the ability of using cultivated land resources. As the trend of cultivated land quality is g...The quality of cultivated land has an important influence on agricultural output, food security, sustainable development and the ability of using cultivated land resources. As the trend of cultivated land quality is getting more and more attention, in order to strengthen the management of cultivated land quality, improve the precision of cultivated land quality and other achievements, and maintain the current situation of cultivated land quality and other achievements. For this paper, taking A county of Guangxi Zhuang Autonomous Region as an example, with the support of GIS, the paper studies the grade and grade renewal of cultivated land by using the superposition method, studies the grade and grade change of regional cultivated land and its spatial distribution, grasps the status quo change of cultivated land and the grade and grade change of cultivated land caused by the quality construction of cultivated land in the year, and then provides scientific data for land use plan, land consolidation and cultivates land protection.展开更多
Oil crops,mainly comprised of soybean,rapeseed,groundnut,sunflower and etc.,have provided substantial edible oil and other tremendous nutrients for human beings,as well as valuable biofuels for associated industries.T...Oil crops,mainly comprised of soybean,rapeseed,groundnut,sunflower and etc.,have provided substantial edible oil and other tremendous nutrients for human beings,as well as valuable biofuels for associated industries.The genetic improvement of significant oil crops and/or domesticating novel high-yielding oil crops are in urgent need to cope with the ever-increasing demand for various oil crop products.CRISPR(Clustered Regularly Interspaced Short Palindromic Repeats)-based genome editing technology,born a few years ago,edits stretches of DNA in a targeted and RNA-dependent fashion.The Characteristics of targeted mutagenesis and easy manipulation owned by the technology make it have been applied to many plants and exhibited great potential in the genetic improvement of many important oil crops.In the face of growing need for oil crop products and the rapid developments in CRISPR-based genome editing technology,a critical review regarding the technology and its application in oil crops is badly required to provide references for the better use of this technology to modify the oil crops for higher yield.In this review paper,we briefly described the CRISPR-based genome editing technology and summarized its applications and future prospects in oil crops.展开更多
A program MVFT3D of large-eddy simulation is developed and performed to solve the multi compressible Navier- Stokes equations. The SGS dissipation and molecular viscosity dissipation have been analyzed, and the former...A program MVFT3D of large-eddy simulation is developed and performed to solve the multi compressible Navier- Stokes equations. The SGS dissipation and molecular viscosity dissipation have been analyzed, and the former is much larger than the later. Our test shows that the SGS dissipation of Vreman model is smaller than the Smagorinsky model. We mainly simulate the experiment of fluid instability of shock-accelerated interface by Poggi in this paper. The decay of the turbulent kinetic energy before the first reflected shock wave–mixing zone interaction and its strong enhancement by re-shocks are presented in our numerical simulations. The computational mixing zone width under double re-shock agreement well with the experiment, and the decaying law of the turbulent kinetic energy is consistent with Mohamed and Larue’s investigation. Also, by using MVFT3D we give some simulation results of the inverse Chevron model from AWE. The numerical simulations presented in this paper allow us to characterize and better understand the Richtmyer-Meshkov instability induced turbulence, and the code MVFT3D is validated.展开更多
Benefiting from the diversity and subjective design feasibility of molecular structure, flexibility,lightweight, molecular level controllability, resource renewability and relatively low cost, polymeric electrode mate...Benefiting from the diversity and subjective design feasibility of molecular structure, flexibility,lightweight, molecular level controllability, resource renewability and relatively low cost, polymeric electrode materials are promising candidates for the next generation of sustainable energy resources and have attracted extensive attention for the foreseeable large scale applications. The conductive polymers have been utilized as electrode materials in the pioneer reports, which, however, have the disadvantages of low stability, low reversibility and slope voltage due to the delocalization of charges in the whole conjugated systems. The discovery of carbonyl materials aroused the interest of organic and polymeric materials for batteries again. This review presents the recent progress in carbonyl polymeric electrode materials for lithium-ion batteries, sodium-ion batteries and magnesium-ion batteries. This comprehensive review is expected to be helpful forarousing more interest of organic materials for metal-ion batteries and designing novel battery materials with high performance.展开更多
基金the National Natural Science Foundation of China(52173163 and 22205069)the National 1000-Talents Program,the Innovation Fund of WNLO,the China Postdoctoral Science Foundation(2021TQ0115 and 2021M701302)+1 种基金Hubei province Postdoctoral Innovation Research Post FundWenzhou Science and Technology Program(ZG2022020,G20220022 and G20220026).
文摘Organic electrode materials are promising for batteries.However,the reported organic electrodes are often facing the challenges of low specific capacity,low voltage,poor rate capability and vague charge storage mechanisms,etc.Isomers are good platform to investigate the charge storage mechanisms and enhance the performance of batteries,which,however,have not been focused in batteries.Herein,two isomers are reported for batteries.As a result,the isomer tetrathiafulvalene(TTF)could store two monovalent anions reversibly,deriving an average discharge voltage of 1.05 V and a specific capacity of 220 mAh g−1 at a current density of 2 C.On the other hand,the other isomer tetrathianaphthalene could only reversibly store one monovalent anion and upon further oxidation,it would undergo an irreversible solid-state molecular rearrangement to TTF.The molecular rearrangement was confirmed by electrochemical performances,X-ray diffraction patterns,nuclear magnetic resonance spectra,and 1H detected heteronuclear multiple bond correlation spectra.These results suggested the small structural change could lead to a big difference in anion storage,and we hope this work will stimulate more attention to the structural design for boosting the performance of organic batteries.
文摘In recent years, with the rapid development of urbanization in China, land acquisition work is particularly important. The division of expropriated area is the primary factor to be considered when evaluating the comprehensive land price of expropriated area. Reasonable division can help to improve the scientific and applicability of the comprehensive land price of the region. How to maximize the protection of farmers’ rights and interests by the division of land requisition is an urgent problem to be solved. Taking Gongcheng Yao Autonomous County as an example, this study adopted the multi-factor comprehensive evaluation method to evaluate the division of land requisition in this area, and carried out the corresponding spatial analysis and data processing based on GIS technology. Gongcheng Yao Autonomous County was divided into levy areas, and the Delphi method was used to screen the impact factors and determine the weight of the levy areas. Reasonable division of land requisition area can provide references for land requisition area, make it more scientific and reasonable, and protect the rights and interests of farmers.
文摘The quality of cultivated land has an important influence on agricultural output, food security, sustainable development and the ability of using cultivated land resources. As the trend of cultivated land quality is getting more and more attention, in order to strengthen the management of cultivated land quality, improve the precision of cultivated land quality and other achievements, and maintain the current situation of cultivated land quality and other achievements. For this paper, taking A county of Guangxi Zhuang Autonomous Region as an example, with the support of GIS, the paper studies the grade and grade renewal of cultivated land by using the superposition method, studies the grade and grade change of regional cultivated land and its spatial distribution, grasps the status quo change of cultivated land and the grade and grade change of cultivated land caused by the quality construction of cultivated land in the year, and then provides scientific data for land use plan, land consolidation and cultivates land protection.
基金National Natural Science Foundation of China(32072098)。
文摘Oil crops,mainly comprised of soybean,rapeseed,groundnut,sunflower and etc.,have provided substantial edible oil and other tremendous nutrients for human beings,as well as valuable biofuels for associated industries.The genetic improvement of significant oil crops and/or domesticating novel high-yielding oil crops are in urgent need to cope with the ever-increasing demand for various oil crop products.CRISPR(Clustered Regularly Interspaced Short Palindromic Repeats)-based genome editing technology,born a few years ago,edits stretches of DNA in a targeted and RNA-dependent fashion.The Characteristics of targeted mutagenesis and easy manipulation owned by the technology make it have been applied to many plants and exhibited great potential in the genetic improvement of many important oil crops.In the face of growing need for oil crop products and the rapid developments in CRISPR-based genome editing technology,a critical review regarding the technology and its application in oil crops is badly required to provide references for the better use of this technology to modify the oil crops for higher yield.In this review paper,we briefly described the CRISPR-based genome editing technology and summarized its applications and future prospects in oil crops.
文摘A program MVFT3D of large-eddy simulation is developed and performed to solve the multi compressible Navier- Stokes equations. The SGS dissipation and molecular viscosity dissipation have been analyzed, and the former is much larger than the later. Our test shows that the SGS dissipation of Vreman model is smaller than the Smagorinsky model. We mainly simulate the experiment of fluid instability of shock-accelerated interface by Poggi in this paper. The decay of the turbulent kinetic energy before the first reflected shock wave–mixing zone interaction and its strong enhancement by re-shocks are presented in our numerical simulations. The computational mixing zone width under double re-shock agreement well with the experiment, and the decaying law of the turbulent kinetic energy is consistent with Mohamed and Larue’s investigation. Also, by using MVFT3D we give some simulation results of the inverse Chevron model from AWE. The numerical simulations presented in this paper allow us to characterize and better understand the Richtmyer-Meshkov instability induced turbulence, and the code MVFT3D is validated.
基金the National 1000-Talents Programthe National Natural Science Foundation of China(Nos. 51773071, 51203067, 51603063)+1 种基金Wuhan Science and Technology Bureau(No. 2017010201010141)the Fundamental Research Funds for the Central Universities(No. HUST: 2017KFYXJJ023)for financial support
文摘Benefiting from the diversity and subjective design feasibility of molecular structure, flexibility,lightweight, molecular level controllability, resource renewability and relatively low cost, polymeric electrode materials are promising candidates for the next generation of sustainable energy resources and have attracted extensive attention for the foreseeable large scale applications. The conductive polymers have been utilized as electrode materials in the pioneer reports, which, however, have the disadvantages of low stability, low reversibility and slope voltage due to the delocalization of charges in the whole conjugated systems. The discovery of carbonyl materials aroused the interest of organic and polymeric materials for batteries again. This review presents the recent progress in carbonyl polymeric electrode materials for lithium-ion batteries, sodium-ion batteries and magnesium-ion batteries. This comprehensive review is expected to be helpful forarousing more interest of organic materials for metal-ion batteries and designing novel battery materials with high performance.
