The considerable utility of organoboranes in synthesis is firmly established,which is in a large part due to the power of the Suzuki-Miyaura cross-coupling reaction for con・structing C-C bonds.Therefore,discovering si...The considerable utility of organoboranes in synthesis is firmly established,which is in a large part due to the power of the Suzuki-Miyaura cross-coupling reaction for con・structing C-C bonds.Therefore,discovering simple new routes to form desirable organoboranes continues to be of significant import.Methodologies that directly transform C-H into C-B are particularly desirable,especially if borylation occurs with excellent site selectivity and without precious metal catalysts due to their low crustal abundance,high cost and toxicity.展开更多
基金supported by the Horizon 2020 Research and Innovation Program (769599)
文摘The considerable utility of organoboranes in synthesis is firmly established,which is in a large part due to the power of the Suzuki-Miyaura cross-coupling reaction for con・structing C-C bonds.Therefore,discovering simple new routes to form desirable organoboranes continues to be of significant import.Methodologies that directly transform C-H into C-B are particularly desirable,especially if borylation occurs with excellent site selectivity and without precious metal catalysts due to their low crustal abundance,high cost and toxicity.
