Xenoliths enclosed in Lavas of the Nyos volcano (Cameroon Volcanic Line, continental sector) range from fertile lherzolites to harzburgites. One spinel-free wehrlite has been also sampled. The occurrence of phlogopite...Xenoliths enclosed in Lavas of the Nyos volcano (Cameroon Volcanic Line, continental sector) range from fertile lherzolites to harzburgites. One spinel-free wehrlite has been also sampled. The occurrence of phlogopites and pargasites in some harzburgites together with specific textural rock-type (lherzolites transitional porphyroclastic to equigranular), including major and trace element compositions both in peridotites bulk rocks and minerals point out interactions between the mantle and basaltic magmas responsible for the formation of wehrlites beneath the Nyos volcano. Hydrous minerals (phlogopites and pargasites) and metasomatic events are their main petrogeochemical signatures different from group 1 samples which are characterized by spoon-shaped REE patterns. Later on, hydrous phases, Ti-rich Cpx, CaO rich Ol, Ti, and V rich Ol wehrlite precipitated from melt enrichments due to the percolation of the mantle by basaltic magmas of alkaline affinity. The metasomatic liquid which percolates the Nyos mantle column was a dense alkaline silicate rich in volatile, displaying low HFSE abundances in the metasomatic hydrous melts compared to the LILE. It is suggested that Nyos mantle peridotites have experienced: 1) variable metasomatic events related to the percolating of the depleted mantle by a alkaline silicate liquid, 2) the spinel-free wehrlite is a group 2 sample corresponding to a cumulate of a similar melt, 3) amphibole may be a potassium-bearing mineral instead of or in addition to phlogopite at shallower levels of Nyos upper mantle and 4) transitional textural rock facies express also the fingerprint of rising mantle plume which were percolated by alkaline magma during their transit to the surface.展开更多
Volcanic deposits from the lake Nyos contain ultramafic xenoliths: lherzolites, harzburgites and wehrlites, sometimes containing amphiboles and phlogopites. The lithospheric mantle beneath Nyos, as inferred from chemi...Volcanic deposits from the lake Nyos contain ultramafic xenoliths: lherzolites, harzburgites and wehrlites, sometimes containing amphiboles and phlogopites. The lithospheric mantle beneath Nyos, as inferred from chemical diagrams, has experienced partial melting and variably cryptic and modal metasomatism of the two groups of samples that have been distinguished: Group 1 samples are characterized by spoon-shaped REE patterns, and Group 2 samples show light (L) REE-enriched patterns. Metasomatic events were associated with pervasive infiltration of volatile (Ti, CO<sub>2</sub>, H<sub>2</sub>O) or alkali-rich small melts fractions and fluids. Later on, hydrous phases, Ti-rich Cpx, CaO-rich Ol, Ti-rich Ol, Cr poor and low values of NiO and F<sub>O</sub> (%) in wehrlite compared to other xenoliths, precipitated from alkali enrichments due to the percolation of the mantle by basaltic magmas. The metasomatic liquid which percolates the Nyos mantle column was a dense alkaline silicate rich in volatile, displaying low HFSE abundances in the metasomatic hydrous melts compared to the LILE. It is suggested that 1) cryptic metasomatism affected Group 1 samples, 2) the spinel-free wehrlite is a Group 2 sample corresponding to a cumulate of a similar melt and 3) amphibole may be a potassium-bearing mineral in addition to phlogopite at shallower levels of Nyos upper mantle. P-T estimated indicates that xenoliths were initially equilibrated in the garnet stability field, at depth of 85 Km, and then they were re-equilibrated in the spinel field owing to isobaric heating up to 1000℃. Adiabatic decompressions occur from 85 to 50 Km materialized by sample NK14 showing transitional porphyroclastic to equigranular texture and displaying pyroxene-Cr spinel symplectites, and from 50 to 30 Km corresponding to 8 - 18 Kbar, pressures in which most xenoliths were incorporated in the host lavas. Therefore, the presence of rising mantle plumes from 85 to 50 Km (sample NK14) and from 50 to 30 Km (all studied samples) is probably related to the evolution of heterogeneous translithospheric mantle diapirs beneath this section of the continental Cameroon Volcanic Line. Local diapirs here may be interpreted as rift-zone initiators.展开更多
The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rock...The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable^(87) Sr/^(86) Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.展开更多
文摘Xenoliths enclosed in Lavas of the Nyos volcano (Cameroon Volcanic Line, continental sector) range from fertile lherzolites to harzburgites. One spinel-free wehrlite has been also sampled. The occurrence of phlogopites and pargasites in some harzburgites together with specific textural rock-type (lherzolites transitional porphyroclastic to equigranular), including major and trace element compositions both in peridotites bulk rocks and minerals point out interactions between the mantle and basaltic magmas responsible for the formation of wehrlites beneath the Nyos volcano. Hydrous minerals (phlogopites and pargasites) and metasomatic events are their main petrogeochemical signatures different from group 1 samples which are characterized by spoon-shaped REE patterns. Later on, hydrous phases, Ti-rich Cpx, CaO rich Ol, Ti, and V rich Ol wehrlite precipitated from melt enrichments due to the percolation of the mantle by basaltic magmas of alkaline affinity. The metasomatic liquid which percolates the Nyos mantle column was a dense alkaline silicate rich in volatile, displaying low HFSE abundances in the metasomatic hydrous melts compared to the LILE. It is suggested that Nyos mantle peridotites have experienced: 1) variable metasomatic events related to the percolating of the depleted mantle by a alkaline silicate liquid, 2) the spinel-free wehrlite is a group 2 sample corresponding to a cumulate of a similar melt, 3) amphibole may be a potassium-bearing mineral instead of or in addition to phlogopite at shallower levels of Nyos upper mantle and 4) transitional textural rock facies express also the fingerprint of rising mantle plume which were percolated by alkaline magma during their transit to the surface.
文摘Volcanic deposits from the lake Nyos contain ultramafic xenoliths: lherzolites, harzburgites and wehrlites, sometimes containing amphiboles and phlogopites. The lithospheric mantle beneath Nyos, as inferred from chemical diagrams, has experienced partial melting and variably cryptic and modal metasomatism of the two groups of samples that have been distinguished: Group 1 samples are characterized by spoon-shaped REE patterns, and Group 2 samples show light (L) REE-enriched patterns. Metasomatic events were associated with pervasive infiltration of volatile (Ti, CO<sub>2</sub>, H<sub>2</sub>O) or alkali-rich small melts fractions and fluids. Later on, hydrous phases, Ti-rich Cpx, CaO-rich Ol, Ti-rich Ol, Cr poor and low values of NiO and F<sub>O</sub> (%) in wehrlite compared to other xenoliths, precipitated from alkali enrichments due to the percolation of the mantle by basaltic magmas. The metasomatic liquid which percolates the Nyos mantle column was a dense alkaline silicate rich in volatile, displaying low HFSE abundances in the metasomatic hydrous melts compared to the LILE. It is suggested that 1) cryptic metasomatism affected Group 1 samples, 2) the spinel-free wehrlite is a Group 2 sample corresponding to a cumulate of a similar melt and 3) amphibole may be a potassium-bearing mineral in addition to phlogopite at shallower levels of Nyos upper mantle. P-T estimated indicates that xenoliths were initially equilibrated in the garnet stability field, at depth of 85 Km, and then they were re-equilibrated in the spinel field owing to isobaric heating up to 1000℃. Adiabatic decompressions occur from 85 to 50 Km materialized by sample NK14 showing transitional porphyroclastic to equigranular texture and displaying pyroxene-Cr spinel symplectites, and from 50 to 30 Km corresponding to 8 - 18 Kbar, pressures in which most xenoliths were incorporated in the host lavas. Therefore, the presence of rising mantle plumes from 85 to 50 Km (sample NK14) and from 50 to 30 Km (all studied samples) is probably related to the evolution of heterogeneous translithospheric mantle diapirs beneath this section of the continental Cameroon Volcanic Line. Local diapirs here may be interpreted as rift-zone initiators.
基金financial support received from Science Education and Research Board(SERB)and Department of Science and Technology(DST)by way of its Young Scientist Scheme(Ref.No.SR/FTP/ES-2/2014)Women’s scientist scheme(Ref No.SR/WOS-A/EA-14/2017)S.Mounic and A.Marquet respectively from Toulouse TIMS and ICPMS facilities.RT acknowledges a"Juan de la Cierva-formación"Fellowship(FJC2018-036729)granted by the Spanish Ministry of Science and Innovation and co-funded by the European Development Fund and the European Social Fund。
文摘The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable^(87) Sr/^(86) Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.