Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions.In particular,the recent designed chiral phosphines based on the concept of bi-/multifunctionalit...Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions.In particular,the recent designed chiral phosphines based on the concept of bi-/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions such as(aza)-MBH reaction/RC reaction,cycloaddition reaction,domino reaction,nucleophilic addition reaction,etc.This review summarizes the recent advances in this field and highlights the selected significant achievements.展开更多
基金We are grateful for the financial support from the Strategic Priority Research Program of the Chinese Academy of Sciences,Grant no.XDB20000000,the National Natural Science Foundation of China(21572052,21421091,21772226,21772037 and 21861132014).
文摘Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions.In particular,the recent designed chiral phosphines based on the concept of bi-/multifunctionality have been demonstrated to be effective catalysts for many types of asymmetric reactions such as(aza)-MBH reaction/RC reaction,cycloaddition reaction,domino reaction,nucleophilic addition reaction,etc.This review summarizes the recent advances in this field and highlights the selected significant achievements.
