Both the accurate distance measurement and positioning information at the nanoscale are important for the analysis of micro/nano interactions.Plasmon ruler has been an indispensable optical tool to detect the chemical...Both the accurate distance measurement and positioning information at the nanoscale are important for the analysis of micro/nano interactions.Plasmon ruler has been an indispensable optical tool to detect the chemical and biological dynamic processes via distance-dependent plasmon coupling in the nearly aggregated state.But it cannot disclose the detailed and accurate information of positions and dynamic movements of its two plasmonic components owing to the inherent diffraction limit.Herein,a plasmonic locator is presented which consists of a heterotypic pair of red/blue plasmonic components with significant wavelength difference(∼150 nm).Attributed to the detuned energy(∼0.64 eV)of the two components,the plasmonic locator has the ability of sub-diffraction-limited resolution(center to center,30 nm)and accurate positioning under conventional dark-field microscopy,making the relative dynamic information of nearby red/blue components be recorded accurately at video rate.As an important complement to the current aggregate science and technology of plasmonics,this newly developed plasmonic locator presents a facile means to realize super-resolution imaging,accurate positioning,and continuous tracing in chemical and biological interactions at the single-molecule level.展开更多
基金National Natural Science Foundation of China,Grant/Award Numbers:21605125,21874109,22134005Natural Science Foundation of Chongqing,Grant/Award Number:cstc2020jcyj-msxmX0992。
文摘Both the accurate distance measurement and positioning information at the nanoscale are important for the analysis of micro/nano interactions.Plasmon ruler has been an indispensable optical tool to detect the chemical and biological dynamic processes via distance-dependent plasmon coupling in the nearly aggregated state.But it cannot disclose the detailed and accurate information of positions and dynamic movements of its two plasmonic components owing to the inherent diffraction limit.Herein,a plasmonic locator is presented which consists of a heterotypic pair of red/blue plasmonic components with significant wavelength difference(∼150 nm).Attributed to the detuned energy(∼0.64 eV)of the two components,the plasmonic locator has the ability of sub-diffraction-limited resolution(center to center,30 nm)and accurate positioning under conventional dark-field microscopy,making the relative dynamic information of nearby red/blue components be recorded accurately at video rate.As an important complement to the current aggregate science and technology of plasmonics,this newly developed plasmonic locator presents a facile means to realize super-resolution imaging,accurate positioning,and continuous tracing in chemical and biological interactions at the single-molecule level.
