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采用TFCA-4PC协同萃取体系从废旧锂离子电池酸浸液中选择性萃取镍
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作者 张立涵 曹佐英 +5 位作者 张贵清 李青刚 王明玉 关文娟 巫圣喜 邓奇 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第4期1311-1320,共10页
采用一种由桐油基羧酸(TFCA)与异烟酸酯(4PC)组成的协同溶剂萃取(SSX)体系,从含Mg/Li的废旧锂离子电池(LIBs)酸浸液中选择性萃取Ni。SSX体系对Ni表现出较强的协同作用,这主要归因于TFCA可以与Ni形成较为稳定的多元螯环结构,因此,体系对N... 采用一种由桐油基羧酸(TFCA)与异烟酸酯(4PC)组成的协同溶剂萃取(SSX)体系,从含Mg/Li的废旧锂离子电池(LIBs)酸浸液中选择性萃取Ni。SSX体系对Ni表现出较强的协同作用,这主要归因于TFCA可以与Ni形成较为稳定的多元螯环结构,因此,体系对Ni的选择性得到增强。在优化条件下,经过单级萃取,Ni的萃取率达到97.3%,而Mg和Li的萃取率分别为0和2.29%。随后,负载有机相经过300mg/LNiSO_(4)洗涤后采用0.2 mol/L H_(2)SO_(4)反萃,获得的反萃液中含有11.52 g/L的Ni和<6 mg/L的Li。 展开更多
关键词 桐油 羧酸萃取剂 协同溶剂萃取 萃取机理
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Development and application of multi-field coupled high-pressure triaxial apparatus for soil
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作者 Xiu-yan wang Lin Sun +6 位作者 Shuai-wei wang ming-yu wang Jin-qiu Li Wei-chao Sun Jing-jing wang Xi Zhu He Di 《Journal of Groundwater Science and Engineering》 2023年第3期308-316,共9页
The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significa... The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster. 展开更多
关键词 Multi-field coupled triaxial test High and low temperature Horizontal deformation Compressed water release
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钒渣提钒和铬循环冶金工艺:(Ⅰ)含铬钒酸盐溶液分离回收钒 被引量:3
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作者 王学文 杨明鄂 +3 位作者 孟钰麒 高大雄 王明玉 付自碧 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第3期807-816,共10页
研究含铬钒酸盐溶液分离回收钒的循环冶金工艺,工艺过程包括溶液中钒的选择性沉淀、沉淀物中钒的浸出及五氧化二钒的制备。在含铬钒酸盐溶液中加入Ca(OH)_(2)进行球磨,不仅可以使其中的钒选择性沉淀析出,而且沉淀物的浸出动力学性能得... 研究含铬钒酸盐溶液分离回收钒的循环冶金工艺,工艺过程包括溶液中钒的选择性沉淀、沉淀物中钒的浸出及五氧化二钒的制备。在含铬钒酸盐溶液中加入Ca(OH)_(2)进行球磨,不仅可以使其中的钒选择性沉淀析出,而且沉淀物的浸出动力学性能得到显著改善。在含铬钒酸盐溶液中按Ca/V摩尔比1.75:1加入Ca(OH)_(2),室温球磨60 min,钒的沉淀率达99.59%,而铬的沉淀率只有0.04%。过滤得到的沉钒渣按液固比4:1 mL/g加水,并按NaHCO_(3)/V摩尔比2.74:1加入NaHCO_(3),室温搅拌60 min,过滤得浸出液,钒的浸出率为99.35%。所得浸出液先通入CO2调pH至8.0,再按NH_(4)HCO_(3)/NaVO_(3)摩尔比1:1加入NH_(4)HCO_(3),室温搅拌8 h结晶析出NH_(4)VO_(3),过滤后,含氨的结晶液重新用于钒酸钙沉淀的浸出,温室搅拌1 h后钒的浸出率>99%,最后,将所得NH_(4)VO_(3)晶体在560℃煅烧2 h得到纯度为99.6%的V_(2)O_(5)。 展开更多
关键词 含铬钒酸盐溶液 钙盐沉钒 碳酸氢钠浸出 铵盐沉钒 循环冶金工艺
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钒渣提钒和铬循环冶金工艺:(Ⅱ)沉钒后液分离回收铬 被引量:5
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作者 杨明鄂 杨皓翔 +2 位作者 田晟晖 王明玉 王学文 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第9期2852-2860,共9页
研究通过用PbCO_(3)沉淀并用Na_(2)CO_(3)溶液浸出从钒沉淀溶液中分离和回收铬的循环冶金工艺。沉钒后液pH调至3.0后,按Pb/Cr摩尔比2.5加入PbCO_(3),在30℃搅拌180 min,铬浓度从2.360 g/L降到0.001 g/L。过滤后,沉铬富集渣用热Na_(2)CO_... 研究通过用PbCO_(3)沉淀并用Na_(2)CO_(3)溶液浸出从钒沉淀溶液中分离和回收铬的循环冶金工艺。沉钒后液pH调至3.0后,按Pb/Cr摩尔比2.5加入PbCO_(3),在30℃搅拌180 min,铬浓度从2.360 g/L降到0.001 g/L。过滤后,沉铬富集渣用热Na_(2)CO_(3)溶液浸出得到含有Na_(2)CrO_(4)的浸出液和含有PbCO_(3)的浸出渣。沉铬富集渣按液固比10:1 mL/g加入到0.5 mol/L的Na_(2)CO_(3)溶液中,调pH到9.5,在70℃搅拌60 min,铬的浸出率为96.43%。过滤后,浸出渣返回沉铬,浸出液循环浸出铬直至Na_(2)CrO_(4)接近饱和。最后,浸出液蒸发结晶后获得Na_(2)CrO_(4)·4H_(2)O产物。 展开更多
关键词 沉钒后液 铅盐沉铬 碳酸钠浸出铬 循环冶金工艺
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V(Ⅳ)-Cr(Ⅲ)-H_2O体系钒铬分离的热力学分析(英文) 被引量:3
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作者 陈边防 黄胜 +4 位作者 刘彪 葛奇 谢舒珊 王明玉 王学文 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第3期567-573,共7页
为了从钒铬还原渣中回收钒和铬,以电位-pH和活度-pH的形式总结298 K时V(Ⅳ)和Cr(Ⅲ)分离的热力学。V-Mn-H_2O体系和Cr-Mn-H_2O体系的电位-pH图表明,MnO_2/Mn^(2+)的电极电位高于VO_2^+/VO^(2+)的电极电位,但是低于Cr_2O_7^(2-)/Cr^(3+)... 为了从钒铬还原渣中回收钒和铬,以电位-pH和活度-pH的形式总结298 K时V(Ⅳ)和Cr(Ⅲ)分离的热力学。V-Mn-H_2O体系和Cr-Mn-H_2O体系的电位-pH图表明,MnO_2/Mn^(2+)的电极电位高于VO_2^+/VO^(2+)的电极电位,但是低于Cr_2O_7^(2-)/Cr^(3+)的电极电位,这表明采用MnO_2来选择性氧化低价钒是可行的。V(Ⅴ)-H_2O体系和Cr(Ⅲ)-H_2O体系的活度-pH图表明,V(Ⅴ)开始沉淀时的pH远低于Cr(Ⅲ)开始沉淀时的pH,因此可以采用沉淀析出法分离V(Ⅴ)和Cr(Ⅲ)。通过热力学分析,设计了钒铬还原渣中分离回收钒和铬的技术路线。 展开更多
关键词 V-Cr-H2O体系 选择性氧化 选择性析出
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A Novel Fuzzy Direct Torque Control System for Three-level Inverter-fed Induction Machine 被引量:2
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作者 Shu-Xi Liu ming-yu wang +1 位作者 Yu-Guang Chert Shan Li 《International Journal of Automation and computing》 EI 2010年第1期78-85,共8页
Diode clamped multi-level inverter (DCMLI) has a wide application prospect in high-voltage and adjustable speed drive systems due to its low stress on switching devices, low harmonic output, and simple structure. Ho... Diode clamped multi-level inverter (DCMLI) has a wide application prospect in high-voltage and adjustable speed drive systems due to its low stress on switching devices, low harmonic output, and simple structure. However, the problem of complexity of selecting vectors and capacitor voltage unbalance needs to be solved when the algorithm of direct torque control (DTC) is implemented on DCMLI. In this paper, a fuzzy DTC system of an induction machine fed by a three-level neutral-point-clamped (NPC) inverter is proposed. After introducing fuzzy logic, optimal selecting switching state is realized by applying various strategies which can distinguish the grade of the errors of stator flux linkage, torque, the neutral-point potential, and the position of stator flux linkage. Consequently, the neutral-point potential unbalance, the dr/dr of output voltage and the switching loss are restrained effectively, and desirable dynamic and steady-state performances of induction machines can be obtained for the DTC scheme. A design method of the fuzzy controller is introduced in detail, and the relevant simulation and experimental results have verified the feasibility of the proposed control algorithm. 展开更多
关键词 Multi-level inverter direct torque control (DTC) fuzzy controller space voltage vector induction machine
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Experimental and numerical investigation of groundwater head losses on and nearby short intersections between disc-shaped fractures
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作者 Ci-xiao Qu ming-yu wang Peng wang 《Journal of Groundwater Science and Engineering》 2022年第1期33-43,共11页
Discrete fracture models are used for investigating precise processes of groundwater flow in fractured rocks,while a disc-shaped parallel-plates model for a single fracture is more reasonable and efficient for computa... Discrete fracture models are used for investigating precise processes of groundwater flow in fractured rocks,while a disc-shaped parallel-plates model for a single fracture is more reasonable and efficient for computational treatments.The flow velocity has a large spatial differentiation which is more likely to produce non-linear flow and additional head losses on and nearby intersections in such shaped fractures,therefore it is necessary to understand and quantify them.In this study,both laboratory experiments and numerical simulations were performed to investigate the total head loss on and nearby the intersections as well as the local head loss exactly on the intersections,which were not usually paid sufficient attention or even ignored.The investigation results show that these two losses account for 29.17%-84.97%and 0-73.57%of the entire total head loss in a fracture,respectively.As a result,they should be necessarily considered for groundwater modeling in fractured rocks.Furthermore,both head losses become larger when aperture and flow rate increase and intersection length decreases.Particularly,the ratios of these two head losses to the entire total head loss in a fracture could be well statistically explained by power regression equations with variables of aperture,intersection length,and flow rates,both of which achieved high coefficients of determination.It could be feasible through this type of study to provide a way on how to adjust the groundwater head from those obtained by numerical simulations based on the traditional linear flow model.Finally,it is practicable and effective to implement the investigation approach combining laboratory experiments with numerical simulations for quantifying the head losses on and nearby the intersections between disc-shaped fractures. 展开更多
关键词 Groundwater head losses Disc-shaped Fracture Laboratory experiments Numerical simulations Short intersections
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Gas release characteristics during carbonization of iron coke hot briquette and influence of heating rate
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作者 Zi-yu wang Dong Han +5 位作者 Zheng-gen Liu Man-sheng Chu Yong-jie Zhang Li-feng Zhang Ji-wei Bao ming-yu wang 《Journal of Iron and Steel Research(International)》 SCIE EI CAS CSCD 2023年第11期2163-2172,共10页
The release characteristics of CH_(4),H_(2),CO and CO_(2) from iron coke hot briquette(ICHB)during carbonization were studied.The results show that compared with briquette without iron ore,Fe_(3)O_(4) can inhibit the ... The release characteristics of CH_(4),H_(2),CO and CO_(2) from iron coke hot briquette(ICHB)during carbonization were studied.The results show that compared with briquette without iron ore,Fe_(3)O_(4) can inhibit the release rate of H2 and promote the production of CO and CO_(2).In addition,when the heating rate increases from 3 to 7℃/min,the release rates of CH4 and H2 increase,while the release rates of CO and CO_(2) first increase and then decrease.The carbonization process of ICHB was segmented,and corresponding kinetic analysis was carried out.The results show that the activation energy of StageⅡand StageⅣis higher in the carbonization process of ICHB,and the active pyrolysis of coal and the reduction of iron ore occur in these two stages.In addition,the effect of heating rate on the kinetic parameters of ICHB carbonization process was investigated.It was found that when the heating rate increased,the reaction activation energy of StageⅣdecreased first and then increased,which was consistent with the release law of CO and CO_(2).The analysis showed that the increase in heating rate leads to more reactions at higher temperatures,resulting in an increase in the release rate of some gases.In addition,thermal hysteresis can also cause some processes to fail to fully react at the end of heating.It is also found that the apparent activation energy and preexponential factor have kinetic compensation effect during the car-bonization of ICHB. 展开更多
关键词 Iron coke hot briquette CARBONIZATION Gas release characteristic Heating rate KINETICS
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温度响应型手性Salen Ti^(IV)嵌段共聚物的可控制备及在硫醚不对称氧化反应中的应用 被引量:2
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作者 张瑶瑶 韩彪 +4 位作者 周丽洁 王明宇 李博解 汪连生 朱磊 《高分子学报》 SCIE CAS CSCD 北大核心 2021年第7期723-733,I0003,共12页
采用可逆加成-断裂链转移自由基聚合法(RAFT),以N-异丙基丙烯酰胺和5-乙烯基手性salen Ti^(IV)为反应单体,偶氮二异丁腈为链引发剂,硫代丙酸苄硫酯为链转移剂,可控制备出一系列温度响应型手性嵌段共聚物(聚N-异丙基丙烯酰胺-co-手性sale... 采用可逆加成-断裂链转移自由基聚合法(RAFT),以N-异丙基丙烯酰胺和5-乙烯基手性salen Ti^(IV)为反应单体,偶氮二异丁腈为链引发剂,硫代丙酸苄硫酯为链转移剂,可控制备出一系列温度响应型手性嵌段共聚物(聚N-异丙基丙烯酰胺-co-手性salen Ti^(IV),PN_(x)S_(y)).通过红外表征证明该嵌段共聚物结构中含有温敏材料和salen Ti^(IV)的特征峰,紫外表征揭示了亲疏水单元比例对嵌段共聚物临界温度LCST的影响,动态光散射证明亲疏水比例对嵌段共聚物水合动力学粒径影响规律.透射电子显微镜和圆二色光谱表征温度对嵌段共聚物自组装的影响,结果表明,接近临界温度30℃时,嵌段共聚物的CD信号最强.该类温度响应型手性嵌段共聚物可实现纯水相中高效不对称反应的进行,仅需0.5 mol%嵌段共聚物催化反应1.0 h,即可实现底物苯甲硫醚转化率达95%,选择性为97%,对映选择性高达98%.实验证明嵌段共聚物在水中可自组装形成纳米反应器,加速反应进行,升温后,嵌段共聚物表现出疏水特性,从水相析出后直接回收,实现了材料可重复利用. 展开更多
关键词 温度响应型 手性嵌段共聚物 纯水相 不对称反应 循环回收利用
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Solvent extraction of molybdenum from acidic leach solution of Ni–Mo ore 被引量:10
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作者 ming-yu wang Xue-Wen wang +1 位作者 Chang-Jun Jiang Chao-Fan Tao 《Rare Metals》 SCIE EI CAS CSCD 2014年第1期107-110,共4页
A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni-Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 ... A P204 (D2EHPA) diluted with sulfonated kerosene was used for the selective extraction of molybdenum from an acidic Ni-Mo ore leach solution that was reduced using sodium thiosulfate. The results indicate that P204 (D2EHPA) is an effective extractant for the extraction of molybdenum. The extraction of Mo is more than 90 % at pH of 0.5, contact time of 10 min, and organic-to- aqueous phase (O/A) ratio of 1:1 with 10 vol% P204 (D2EHPA). Molybdenum in the loaded organic phase can be effectively stripped with ammonium acid carbonate solution, and the stripping of molybdenum with 60 g.L-1 ammonium acid carbonate solution is 94.67 % at O/A ratio of 2:1 and contact time of 10 min. 展开更多
关键词 MOLYBDENUM Ni-Mo ore Solvent extraction P204 (D2EHPA)
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Effect of Yangxinshi Tablets on the Phenotype and Function of Monocytes in Patients with Unstable Angina Pectoris of Coronary Heart Disease 被引量:8
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作者 Li-Na Yang ming-yu wang +3 位作者 Ya-Qi Tong Shu-Nan Zhang Wei-Xia Wu Yan-Chun Ding 《World Journal of Traditional Chinese Medicine》 2020年第2期216-226,共11页
Objective:The objective of this study was to observe the effect of Yangxinshi tablets on the phenotype and function of peripheral blood monocytes in patients with unstable angina of coronary heart disease(CHD)and to e... Objective:The objective of this study was to observe the effect of Yangxinshi tablets on the phenotype and function of peripheral blood monocytes in patients with unstable angina of coronary heart disease(CHD)and to explore the possible mechanism of Yangxinshi tablets in the treatment of CHD.Methods:A total of 100 patients with unstable angina of CHD were randomly divided into two groups:Group A–treatment group and Group B–control group.The phenotypic and functional changes in blood monocytes and the changes in serum inflammatory factors before and after treatment were compared in the two groups.Results:The expression of CD14^+CD163^+interleukin(IL)-10^+was significantly higher in the control group than in the patients with unstable angina of CHD,whereas the expression of CD14^+CD163-IL-12^+was lower.The concentration of IL-10 was higher in the control group than in the patients with unstable angina,whereas the concentration of tumor necrosis factor-α(TNF-α)and IL-12 was significantly lower.In Group A,the expression of CD14^+CD163^+,CD14^+CD206^+,and CD14^+CD163^+CD206^+in peripheral blood monocytes increased after treatment than before treatment,whereas the expression of CD14^+CD163-CD206-decreased.The expression of CD14^+CD163-IL-12^+decreased after treatment than before,whereas CD14^+CD163^+IL-10^+expression increased.The serum concentration of IL-10 in Group A was higher after treatment than before,whereas that of IL-12 and TNF-αwas lower.In Group B,the phenotype and function of the peripheral blood monocytes remained unchanged.Conclusion:Yangxinshi tablet therapy can change the phenotype of the peripheral blood monocytes in patients with unstable angina of CHD.Yangxinshi tablet therapy changes the inflammatory state in patients with an increase in the expression of anti-inflammatory factors and a decrease in the expression of inflammatory factors. 展开更多
关键词 Coronary heart disease inflammatory factor monocyte phenotype unstable angina Yangxinshi tablets
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Existing form of Mo(Ⅵ)in acidic sulfate solution 被引量:1
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作者 ming-yu wang Chang-Jun Jiang +3 位作者 Xue-Wen wang Peng-Fei Xian Hua-Guang wang Yang Yang 《Rare Metals》 SCIE EI CAS CSCD 2017年第7期612-616,共5页
The existing form of molybdenum in acidic sulfate solution was studied by means of ion exchange, infrared (IR) spectra and X-ray photoelectron spectroscopy (XPS). The results indicate that the anionic molybdenum s... The existing form of molybdenum in acidic sulfate solution was studied by means of ion exchange, infrared (IR) spectra and X-ray photoelectron spectroscopy (XPS). The results indicate that the anionic molybdenum species are predominant in acidic sulfate solution, and Mo(VI) can combine with sulfate radical to form heteropoly acid anions [Mo205(804)2]2- and [MoO2(HSO4)4]2-. With the decrease in solution pH from 1.92 to 0.06, the existing form of Mo(VI) changes from MovO21(OH)3^3- to [Mo205(S04)2]2- and then becomes [MoOz(HSO4)4]2-, which results in the decrease in the resin adsorption capacity for molybdenum. 展开更多
关键词 MOLYBDENUM Acidic sulfate solution Ionexchange
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