Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs) ...Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs) of agricultural soil, within a radius of 3 km from a municipal solid waste incinerator (MSWI) plant after its 4-year operation in Hangzhou, China. Comparisons were made between the measured and estimated congener-specific concentrations and the international-toxic equivalent (I-TEQ) values of soil samples with respect to distance from the stack. The results indicate that the predictions of soil PCDD/F concentrations and I-TEQ values were generally lower than their observations, and that the higher the degree of under-estimation seems, the greater the further downwind one gets. Nevertheless, most of the predictions were in good agreement with the trend of measured ones and were within a factor of ten for samples located within 1 km of the plant. Besides, analysis of contributions of various deposition pathways confirms that in addition to wet particle deposition, the dry gaseous deposition is essential for realistic prediction of PCDD/F depositions to soil, especially for tetra-and penta-chlorinated dioxins.展开更多
In this study, a porous inserted regenerative thermal oxidizer (PRTO) system was developed for a 125 kW industrial copper-melting furnace, due to its advantages of low NO x emissions and high radiant efficiency. Zirco...In this study, a porous inserted regenerative thermal oxidizer (PRTO) system was developed for a 125 kW industrial copper-melting furnace, due to its advantages of low NO x emissions and high radiant efficiency. Zirconium dioxide (ZrO2 ) ceramic foams were placed into the combustion zone of a regenerative thermal oxidizer (RTO). Different performance characteristics of the RTO and PRTO systems, including pressure drop, temperature distribution, emissions, and energy efficiency, were evaluated to study the effects of the porous inserts on non-premixed CH4 combustion. It was found that the PRTO system achieved a significant reduction in the NOx emission level and a fuel saving of approximately 30% compared to the RTO system. It is most suitable for a lean combustion process at an equivalence ratio <0.4 with NOx and CO emission levels within 0.002%-0.003% and 0.001%-0.002%, respectively.展开更多
The naphthalene decomposition in a corona radical shower discharge (CRS) was investigated, with attention paid to the influences of voltage and initial naphthalene density. The OH emission spectra were investigated so...The naphthalene decomposition in a corona radical shower discharge (CRS) was investigated, with attention paid to the influences of voltage and initial naphthalene density. The OH emission spectra were investigated so as to know the naphthalene decomposing process. The by-products were analyzed and a decomposing theory in discharge was proposed. The results showed that higher voltage and relative humidity were effective on decomposition. The initial concentration affected the decomposing efficiency of naphthalene. When the initial naphthalene density was 17 mg/m3, the decomposition rate was found to be 70% under 14 kV. The main by-products were carbon dioxide and water. However, a small amount of carbonic oxide, 1,2-ethanediol and acetaldehyde were found due to the incomplete oxidization.展开更多
基金Project (Nos. X506312 and X206955) supported by the NaturalScience Foundation of Zhejiang Province, China
文摘Based on the Industrial Source Complex Short-Term Version 3 (ISCST3) model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs) of agricultural soil, within a radius of 3 km from a municipal solid waste incinerator (MSWI) plant after its 4-year operation in Hangzhou, China. Comparisons were made between the measured and estimated congener-specific concentrations and the international-toxic equivalent (I-TEQ) values of soil samples with respect to distance from the stack. The results indicate that the predictions of soil PCDD/F concentrations and I-TEQ values were generally lower than their observations, and that the higher the degree of under-estimation seems, the greater the further downwind one gets. Nevertheless, most of the predictions were in good agreement with the trend of measured ones and were within a factor of ten for samples located within 1 km of the plant. Besides, analysis of contributions of various deposition pathways confirms that in addition to wet particle deposition, the dry gaseous deposition is essential for realistic prediction of PCDD/F depositions to soil, especially for tetra-and penta-chlorinated dioxins.
文摘In this study, a porous inserted regenerative thermal oxidizer (PRTO) system was developed for a 125 kW industrial copper-melting furnace, due to its advantages of low NO x emissions and high radiant efficiency. Zirconium dioxide (ZrO2 ) ceramic foams were placed into the combustion zone of a regenerative thermal oxidizer (RTO). Different performance characteristics of the RTO and PRTO systems, including pressure drop, temperature distribution, emissions, and energy efficiency, were evaluated to study the effects of the porous inserts on non-premixed CH4 combustion. It was found that the PRTO system achieved a significant reduction in the NOx emission level and a fuel saving of approximately 30% compared to the RTO system. It is most suitable for a lean combustion process at an equivalence ratio <0.4 with NOx and CO emission levels within 0.002%-0.003% and 0.001%-0.002%, respectively.
基金Project supported by the National Basic Research Program (973) of China (No.2006CB200303)the Chinese-Slovak Scientific and Technological Cooperation Program (No.2010DFA92020)the China Postdoctoral Science Foundation (No.20100471698)
文摘The naphthalene decomposition in a corona radical shower discharge (CRS) was investigated, with attention paid to the influences of voltage and initial naphthalene density. The OH emission spectra were investigated so as to know the naphthalene decomposing process. The by-products were analyzed and a decomposing theory in discharge was proposed. The results showed that higher voltage and relative humidity were effective on decomposition. The initial concentration affected the decomposing efficiency of naphthalene. When the initial naphthalene density was 17 mg/m3, the decomposition rate was found to be 70% under 14 kV. The main by-products were carbon dioxide and water. However, a small amount of carbonic oxide, 1,2-ethanediol and acetaldehyde were found due to the incomplete oxidization.
基金supported by the National Natural Science Foundation of China(No.51366010)the Inner Mongolia Autonomous Region Open Major Basic Research Project(No.20120905),China