期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
多孔铂纳米管用于水溶液中乙醇的电化学重整 被引量:4
1
作者 王天娇 孙绘滢 +6 位作者 薛淇 钟明君 李富民 田新龙 陈沛 尹诗斌 陈煜 《Science Bulletin》 SCIE EI CSCD 2021年第20期2079-2089,M0003,共12页
铂纳米结构的催化/电催化性能与其形貌密切相关.在此,本文提出一种简单的高温自模板法热解策略,以丁二酮肟铂络合物(Pt^(Ⅱ)-DMG)纳米棒为反应前驱体合成一维多孔Pt纳米管(Pt-hNTs).DMG的强配位能力导致Pt^(Ⅱ)-DMG纳米棒生成,而DMG的... 铂纳米结构的催化/电催化性能与其形貌密切相关.在此,本文提出一种简单的高温自模板法热解策略,以丁二酮肟铂络合物(Pt^(Ⅱ)-DMG)纳米棒为反应前驱体合成一维多孔Pt纳米管(Pt-hNTs).DMG的强配位能力导致Pt^(Ⅱ)-DMG纳米棒生成,而DMG的高温还原性导致了Pt^(Ⅱ)-DMG中Pt^(Ⅱ)物种的还原.在合成过程中,由内而外的奥斯特瓦尔德熟化作用使得Pt-hNTs具有中空的结构;同时,空气中的氧气能有效去除Pt-hNTs表面的碳或/和碳氧化物而形成清洁表面.得益于其中空和多孔的物理特性,表面清洁的Pt-hNTs具有高比表面积、高自稳定性和快速的传质效率,使其在碱性介质中对于催化乙醇电氧化和析氢反应表现出良好的活性和稳定性.在优化的实验条件下,构建的Pt-hNTs||Pt-hNTs乙醇电解槽仅需0.4 V的电解电压即可实现电解水制氢.本工作不仅提供了一种简单高效的中空多孔Pt纳米管的合成策略,而且表明Pt-hNTs具有优异的活性和稳定性,其可应用于其他能源/环境相关的催化体系. 展开更多
关键词 电解水制氢 碳氧化物 析氢反应 电解电压 传质效率 丁二酮肟 自稳定性 自模板法
原文传递
Hot deformation behavior and process parameters optimization of Ti-6Al-7Nb alloy using constitutive modeling and 3D processing map 被引量:2
2
作者 ming-jun zhong Ke-lu Wang +3 位作者 Shi-qiang Lu Xin Li Xuan Zhou Rui Feng 《Journal of Iron and Steel Research(International)》 SCIE EI CSCD 2021年第7期862-873,共12页
The isothermal compression test for Ti-6Al-7Nb alloy was conducted by using Gleeble-3800 thermal simulator.The hot deformation behavior of Ti-6Al-7Nb alloy was investigated in the deformation temperature ranges of 940... The isothermal compression test for Ti-6Al-7Nb alloy was conducted by using Gleeble-3800 thermal simulator.The hot deformation behavior of Ti-6Al-7Nb alloy was investigated in the deformation temperature ranges of 940-1030℃and the strain rate ranges of 0.001-10 s^(-1).Meanwhile,the activation energy of thermal deformation was computed.The results show that the flow stress of Ti-6Al-7Nb alloy increases with increasing the strain rate and decreasing the deformation temperature.The activation energy of thermal deformation for Ti-6Al-7Nb alloy is much greater than that for self-diffusion ofα-Ti andβ-Ti.Considering the influence of strain on flow stress,the strain-compensated Arrhenius constitutive model of Ti-6Al-7Nb alloy was established.The error analysis shows that the model has higher accuracy,and the correlation coefficient r and average absolute relative error are 0.9879 and 4.11%,respectively.The processing map(PM)of Ti-6Al-7Nb alloy was constructed by the dynamic materials model and Prasad instability criterion.According to PM and microstructural observation,it is found that the main form of instability zone is local flow,and the deformation mechanisms of the stable zone are mainly superplasticity and dynamic recrystallization.The optimal processing parameters of Ti-6Al-7Nb alloy are determined as follows:960-995℃/0.01-0.18 s^(-1)and 1000-1030℃/0.001-0.01 s^(-1). 展开更多
关键词 Ti-6Al-7Nb alloy Hot deformation behavior Strain-compensated Arrhenius constitutive model Processing map Process parameters optimization
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部