A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The...A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The morphology,structure and photoelectrochemical properties of the photocatalysts were characterized by means of SEM,TEM,XRD,XPS,FT-IR,BET,PL,UV-vis/DRS,and EIS techniques.The results showed that the introduction of BC significantly enhanced the photocatalytic activity.When the content of biomass carbon(BC)in a composite is 3%(based on the mass of BiOBr),the obtained BiOBr@BC-3 exhibits excellent photocatalytic activity,degrading 99%of RhB within 20 min.The excellent degradation efficiency after the introduction of BC can be attributed to the enhanced visible light absorption,narrower band gap,and fast electron-hole pair separation rate.The photocatalytic mechanism on the degradation of RhB was illustrated based on the radicals'trapping experiments and semiconductor energy band position.The proposed material is expected to be of significant application value in the field of wastewater treatment.展开更多
Friction and wear are unavoidable in mechanical movement.The use of lubricants with nano-additives can effectively reduce friction and wear,which is of great significance to saving energy and protecting the environmen...Friction and wear are unavoidable in mechanical movement.The use of lubricants with nano-additives can effectively reduce friction and wear,which is of great significance to saving energy and protecting the environment.At present,great progress has been made in the scientific research and industrial application of nano-additives for lubricants.This paper mainly introduces the types of nano-additives for lubricants(such as carbon nanomaterials,nano-metals,nano-oxides,sulfides,complexes,polymers,etc.),the tribological properties of lubricants with different components of nano-additives,and the lubrication mechanisms of the nano-additives(including tribofilm formation,rolling ball bearing effect,repairing effect,polishing effect,and synergistic effect).It also deals with the dispersion of nano-additives in lubricants and the influences of their particle size and microstructure on the tribological properties of lubricants.This review outlines the performance requirements of nano-additives in different lubrication states,discusses the use of nano-additives in challenging working conditions,and identifies various industrial oil nano-additives with reference to the appropriate options in diverse working environments.Furthermore,the existing problems of nano-additives and their application prospects are summarized.This review,hopefully,would help to shed light on the design and synthesis of novel high-performance nano-additives and promote their application in engineering.展开更多
基金the National Natural Science Foundation of China(51572185)Natural Science Foundation of Shanxi Province(202203021211158 and 20210302123176)+1 种基金the Key Research&Development Program of Shanxi Province(Social Development,201903D321060)the Key Research&Development program of Shanxi Province(International Cooperation,201903D421079)for the financial support.
文摘A series of BiOBr@biomass carbon derived from locust leaves materials(BiOBr@BC)were fabricated and the photocatalytic property was investigated for photocatalytic degradation of rhodamine B(RhB)under visible light.The morphology,structure and photoelectrochemical properties of the photocatalysts were characterized by means of SEM,TEM,XRD,XPS,FT-IR,BET,PL,UV-vis/DRS,and EIS techniques.The results showed that the introduction of BC significantly enhanced the photocatalytic activity.When the content of biomass carbon(BC)in a composite is 3%(based on the mass of BiOBr),the obtained BiOBr@BC-3 exhibits excellent photocatalytic activity,degrading 99%of RhB within 20 min.The excellent degradation efficiency after the introduction of BC can be attributed to the enhanced visible light absorption,narrower band gap,and fast electron-hole pair separation rate.The photocatalytic mechanism on the degradation of RhB was illustrated based on the radicals'trapping experiments and semiconductor energy band position.The proposed material is expected to be of significant application value in the field of wastewater treatment.
基金National Natural Science Foundation of China(21805085)The Key Technologies R&D Program of Henan Province(212102210039)+2 种基金Scientific and Technological Innovation Team of Henan Province University(22IRTSTHN018)Zhongyuan Science and Technology Innovation Leadership Program(214200510024)Visiting Professor Fund Project of North China University of Water Resources and Electric Power(4001-40734).
文摘Friction and wear are unavoidable in mechanical movement.The use of lubricants with nano-additives can effectively reduce friction and wear,which is of great significance to saving energy and protecting the environment.At present,great progress has been made in the scientific research and industrial application of nano-additives for lubricants.This paper mainly introduces the types of nano-additives for lubricants(such as carbon nanomaterials,nano-metals,nano-oxides,sulfides,complexes,polymers,etc.),the tribological properties of lubricants with different components of nano-additives,and the lubrication mechanisms of the nano-additives(including tribofilm formation,rolling ball bearing effect,repairing effect,polishing effect,and synergistic effect).It also deals with the dispersion of nano-additives in lubricants and the influences of their particle size and microstructure on the tribological properties of lubricants.This review outlines the performance requirements of nano-additives in different lubrication states,discusses the use of nano-additives in challenging working conditions,and identifies various industrial oil nano-additives with reference to the appropriate options in diverse working environments.Furthermore,the existing problems of nano-additives and their application prospects are summarized.This review,hopefully,would help to shed light on the design and synthesis of novel high-performance nano-additives and promote their application in engineering.