Ultrasonic cavitation-enabled microfluidic approach toward the continuous synthesis of cesium lead halide perovskite nanocrystals

Ligand assisted reprecipitation(LARP)is a widely used method for cesium lead halide perovskite nanocrystals(NCs)synthesis.Nevertheless,the ultrafast kinetics of LARP,as well as the inefficient transport properties and discontinuity of batch reactors,challenge the particle size control and experimental repeatability.To address these issues,an ultrasonic cavitation-enabled microfluidic approach was developed to achieve the continuous synthesis of cesium lead halide perovskite via LARP.It was found that the mixing between the good solvent and antisolvent in the microchannel was greatly enhanced by intensive ultrasonic cavitation.The mixing time could be reduced to below 10 ms under the irradiation of 35 W ultrasound.By modulating the mixing degree,LARP was proved to be a mixing-sensitive process.The effects of ultrasonic power,ultrasonic treatment time,total flow rate,water additive,and reprecipitation temperature on the synthesis of CsPbBr_(3) NCs were systematically investigated.As compared to CsPbBr_(3) NCs synthesized in the batch reactor,the sample synthesized via the ultrasonic cavitation-enabled microfluidic approach possessed stronger photoluminescence intensity and better repeatability.Moreover,the ultrasonic cavitation-enabled microfluidic approach could also realize the continuous synthesis of cesium lead halide perovskite NCs with different halide compositions to cover a wide visible spectrum(426-661 nm).The ultrasonic cavitation-enabled microfluidic approach paved the way for the large-scale of high-quality cesium lead halide perovskite NCs.

气田抗硫高压分离器的流场稳态分析

高压分离器是气田生产中的重要设备。它承受高压,属于压力容器。本文采用CATIA软件建立设备的完整三维模型。然后利用fluent软件,对分离器内部的流场进行了有限元分析计算。结果表明,结构内部的速度场和压力场都变化不大。分离器内部的伞型罩帽不会改变分离器内部的速度场和压力场。从分离器承压角度考虑,建议在天然气入口位置增加遮挡板。

Experimental and Numerical Study on the Gas Explosion in Urban Regulator Station

Regulator station is an important part in the urban gas transmission and distribution system.Once gas explosion occurs,the real explosion process and consequences of methane gas explosion in the regulator station were not revealed systematically.In this study,a full-scale experiment was carried out to simulate the regulator station explosion process,and some numerical simulations with a commercial CFD software called FLACS were conducted to analyze the effect of ignition and vent conditions on the blast overpressure and flame propagation.The experimental results demonstrated that the peak overpressure increased as the distance from the vent increased within a certain distance.And the maximum overpressure appeared 3 m away from the door,which was about 36.6 kPa.It was found that the pressure-time rising curves obtained from the simulation are basically the same as the ones from the experiment,however,the time of reaching the peak pressure was much shorter.The numerical simulation results show that the peak overpressures show an increase trend as the ignition height decreased and the vent relief pressure increased.It indicates that the damage and peak overpressure of gas explosion could be well predicted by FLACS in different styles of regulator station.In addition,the results help us to understand the internal mechanism and development process of gas explosion better.It also offers technical support for the safety protection of the urban regulator station.

Boundary Induced Inductive Delay in Transmission of Electromagnetic Signals

When an electromagnetic signal transmits through a coaxial cable, it propagates at speed determined by the dielectrics of insulator between the cooper core wire and the metallic shield. However, we demonstrate here that, once the shielding layer of the coaxial cable is cut into two parts leaving a small gap, while the copper core wire is still perfectly connected, a remarkable transmission delay immediately appears in the system. We have revealed by both computational simulation and experiments that, when the gap spacing between two parts of the shielding layer is small, this delay is mostly determined by the overall geometrical parameters of the conductive boundary which connects two parts of the cut shielding layer. A reduced analytic formula for the transmission delay related with geometrical parameters, which is based on an inductive model of the transmission system, matches well with the fitted formula of the simulated delay. This above structure is analog to the situation that an interconnect is between two inter-modules in a circuit. The results suggest that for high speed circuits and systems, parasitic inductance should be taken into full consideration, and compact conductive packaging is favorable for reducing transmission delay of inter-modules, therefore enhancing the performance of the system.

Research Progress on the <i>Actinomyces arthrobacter</i>

The genus Arthrobacter was established in 1947 by Conn & Dimmick. So far, more than 70 recognized?species of the genus Arthrobacter have been certified. Its special functions have been widely known by researchers, such as, in agricultural, in medical, in industrial, and in environmental areas, etc. What deserves to be mentioned is that some species of genus Arthrobacter have showed the function of degrading pesticides, fixing nitrogen, producing beneficial enzyme, treating sewage, and so on. Recently, the applications of the genus Arthrobacter, especially the VBNC?(viable but non-culturable) bacteria of this genus in the field of contaminated environment repair attract people’s attention and some related research results have also been obtained. The functions that we have known are waiting for us to study about mechanism, deeply. And, we can look forward to discovering more potential functions and applications of this genus in ecological environment. In the meantime, these discoveries must bring more new changes and knowledge.

Development of a deviation package method for low-cost robust optimization in compressor blade design

Manufacture variations can greatly increase the performance variability of compressor blades. Current robust design optimization methods have a critical role in reducing the adverse impact of the variations, but can be affected by errors if the assumptions of the deviation models and distribution parameters are inaccurate. A new approach for robust design optimization without the employment of the deviation models is proposed. The deviation package method and the interval estimation method are exploited in this new approach. Simultaneously, a stratified strategy is used to reduce the computational cost and assure the optimization accuracy. The test case employed for this study is a typical transonic compressor blade profile, which resembles most of the manufacture features of modern compressor blades. A set of 96 newly manufactured blades was measured using a coordinate measurement machine to obtain the manufacture variations and produce a deviation package. The optimization results show that the scatter of the aerodynamic performance for the optimal robust design is 20% less than the baseline value. By comparing the optimization results obtained from the deviation package method with those obtained from widely-used methods employing the deviation model, the efficiency and accuracy of the deviation package method are demonstrated. Finally, the physical mechanisms that control the robustness of different designs were further investigated, and some statistical laws of robust design were extracted.

Probing non-polarizable liquid/liquid interfaces using scanning ion conductance microscopy

The study of microscopic structure of a liquid/liquid interface is of fundamental importance due to its close relation to the thermodynamics and kinetics of interfacial charge transfer reactions.In this article,the microscopic structure of a non-polarizable water/nitrobenzene(W/NB)interface was evaluated by scanning ion conductance microscope(SICM).Using SICM with a nanometer-sized quartz pipette filled with an electrolyte solution as the probe,the thickness of this type of W/NB interface could be measured at sub-nanometer scale,based on the continuous change of ionic current from one phase to another one.The effects for thicknesses of the non-polarizable W/NB interfaces with different electrolyte concentrations,the Galvani potentials at the interface and the applied potentials on the probe were measured and systematically analyzed.Both experimental setups,that is an organic phase up and an aqueous down,and a reverse version,were employed to acquire the approach curves.These data were compared with those of an ideal polarizable interface under the similar experimental conditions,and several characteristics of non-polarizable interfaces were found.The thickness of a non-polarizable interface increases with the decrease of electrolyte concentration and the increase of applied potential,which is similar to the situation of a polarizable liquid/liquid interface.We also find that the Galvani potential across a non-polarizable interface can also influence the interfacial thickness,this phenomenon is difficult to observe when using polarizable interface.Most importantly,by the comparison of two kinds of liquid/liquid interfaces,we experimentally proved that much more excess ions are gathered in the space charge layer of non-polarizable interfaces than in that of polarizable interfaces.These results are consistent with the predictions of molecular dynamic simulations and X-ray reflectivity measurements.

Analysis of minimum specific energy consumption and optimal transport concentration of slurry pipeline transport systems

Slurry pipeline transport is widely used in several industrial processes.Calculating the specific power consumption(SPC)and determining the best working conditions are important for the design and operation of transportation systems.Based on the Shanghai Jiao Tong University high-concentration multi-sized slurry pressure drop(SJTU-HMSPD)pipeline-resistance-calculation model,the SJTU-SPC model for calculating the power required to transport a unit volume of solid materials over a unit pipeline length is established for a slurry transport system.The said system demonstrates a uniformity coefficient in the 1.26–7.98 range,median particle size of 0.075–4 mm,particle volume concentration of 10–60%,and pipeline diameter of 0.203–0.8 m.The results obtained were successfully verified against existing experimental data.The influence of parameters,such as particle-gradation uniformity coefficient,median particle size,pipe diameter,and particle volume concentration,on the SPC were analysed.The results revealed that the greater is the uniformity coefficient,the smaller is the minimum specific energy consumption and the larger the optimal transport concentration for a constant,median particle size slurry.As observed,the optimal transport concentration for broad-graded sand equalled approximately 48%.These results supplement the conclusions of existing research,indicating that the optimal transport concentration is approximately 30%and provides theoretical support for high concentration transportation of broad graded slurry.

微反应器内Stöber法可控制备SiO_(2)微球

采用微反应器与间歇反应器串联策略,实现了反应物料的快速混合及陈化时间的灵活调变,基于St?ber法可控合成了SiO_(2)微球。通过X射线粉末衍射(XRD)、傅里叶变换红外光谱(FT-IR)、透射电子显微镜(TEM)对样品的物相和形貌进行了表征。结果表明,SiO_(2)微球的平均粒径及粒径分布取决于TEOS水解反应及硅酸盐单体缩聚反应间的竞争,同时还受反应前期物料的混合速率的显著影响。当陈化温度从25℃增高至75℃,SiO_(2)微球平均粒径从472 nm减小至200 nm,单分散性变化不大。当氨水浓度从0.8 mol/L增加至5.6 mol/L时,SiO_(2)微球平均粒径从34 nm增大至261 nm,单分散性变好。当水浓度增加至35.6 mol/L或TEOS浓度增加至1.0 mol/L时,溶液中发生多次成核或持续成核现象,使得SiO_(2)微球的单分散性急剧变差。提高雷诺数或缩小通道内径有利于获得单分散SiO_(2)微球。