Bio-based polyurethanes(PUs)have been occurred a large attention nowadays.It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence,availability,good pric...Bio-based polyurethanes(PUs)have been occurred a large attention nowadays.It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence,availability,good price and biodegradability.In addition,the nature shows several bio-derived compounds as raw materials for the synthesis of polyols,including the vegetable oils,polyphenol,terpene,and other bio-renewable sources.With the aim to develop a new family of biobased polyurethanes(PUs)via vegetable oils,the elaboration of new Jojoba-based PUs was performed by catalyst-free polycondensation reaction of a synthesized Jojoba diol with various diisocyanates such us toluene diisocyanate(TDI)and isophorone diisocyanate(IPDI).All the compounds were characterized by FTIR and NMR spectroscopies,and their properties were determined by gel permeation chromatography,differential scanning calorimetry and thermogravimetric analysis.The obtained results show renewable vegetable oils-based PUs materials can be preparing using a new environmentally ways and giving various good properties performances.展开更多
Two distinct lignocellulosic fractions(rind and core)can be obtained through a physical separation of sugarcane stalks.Although presenting differences in morphology,both fractions can be employed to produce pulps and ...Two distinct lignocellulosic fractions(rind and core)can be obtained through a physical separation of sugarcane stalks.Although presenting differences in morphology,both fractions can be employed to produce pulps and papers.The pulps and paper sheets produced from the core and rind fractions were characterized by their chemical composition,physical properties and mechanical properties.The pulps obtained from the core presented a higher amount of fines,lower drainage ability and rendered denser and stiffer sheets.The pulps from the rind,which have a higher content of fibers and higher degree of polymerization,produced sheets with higher air permeability and water absorption.Both paper sheets presented mechanical and physical properties comparable to commercial papers and papers from different cellulosic sources.The different properties exhibited by the papers produced from each fraction allow their use for distinct purposes,and expands the opportunities in the context of sugarcane biorefinery.展开更多
基金the“CMPTM Project 17TM22”and to the“PHC-UTIQUE CMCU”(18G1132)the Tunisian Ministry of Higher Education and LabEx Tec 21 for the financial support.
文摘Bio-based polyurethanes(PUs)have been occurred a large attention nowadays.It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence,availability,good price and biodegradability.In addition,the nature shows several bio-derived compounds as raw materials for the synthesis of polyols,including the vegetable oils,polyphenol,terpene,and other bio-renewable sources.With the aim to develop a new family of biobased polyurethanes(PUs)via vegetable oils,the elaboration of new Jojoba-based PUs was performed by catalyst-free polycondensation reaction of a synthesized Jojoba diol with various diisocyanates such us toluene diisocyanate(TDI)and isophorone diisocyanate(IPDI).All the compounds were characterized by FTIR and NMR spectroscopies,and their properties were determined by gel permeation chromatography,differential scanning calorimetry and thermogravimetric analysis.The obtained results show renewable vegetable oils-based PUs materials can be preparing using a new environmentally ways and giving various good properties performances.
文摘Two distinct lignocellulosic fractions(rind and core)can be obtained through a physical separation of sugarcane stalks.Although presenting differences in morphology,both fractions can be employed to produce pulps and papers.The pulps and paper sheets produced from the core and rind fractions were characterized by their chemical composition,physical properties and mechanical properties.The pulps obtained from the core presented a higher amount of fines,lower drainage ability and rendered denser and stiffer sheets.The pulps from the rind,which have a higher content of fibers and higher degree of polymerization,produced sheets with higher air permeability and water absorption.Both paper sheets presented mechanical and physical properties comparable to commercial papers and papers from different cellulosic sources.The different properties exhibited by the papers produced from each fraction allow their use for distinct purposes,and expands the opportunities in the context of sugarcane biorefinery.
