The Cu(I)‐catalyzed cascade coupling/cyclization reaction of N‐tosylhydrazones with 3‐butyn‐1‐ol has been explored. This new strategy represents a simple platform for the synthesis of tetrahydrofurans in moderate...The Cu(I)‐catalyzed cascade coupling/cyclization reaction of N‐tosylhydrazones with 3‐butyn‐1‐ol has been explored. This new strategy represents a simple platform for the synthesis of tetrahydrofurans in moderate to good yields.展开更多
Black carbon(BC)is one of the major aerosol components with relatively high implications on climatic patterns through its radiative forcing(RF).South Asia has recently experienced an increased concentration of polluti...Black carbon(BC)is one of the major aerosol components with relatively high implications on climatic patterns through its radiative forcing(RF).South Asia has recently experienced an increased concentration of pollution;however,relatively fewer studies have been carried out on long-term assessment of BC and its implications.The present study analyzed the long-term concentration of BC in selected urban locations over South Asia using the Modern-Era Retrospective analysis for Research and Applications,version 2(MERRA-2).The study employed statistical analysis,including linear regression techniques,to assess the long-term concentration of BC.The results show that a rapid increase of BC is observed over most urban locations of South Asia with the predominance in winter and hence requires strict regional control measures to reduce the excess concentration of BC in the atmosphere.High concentration of BC in winter is attributed to anthropogenic activities and changes in meteorological conditions that enhance the accumulation of pollutants in the atmosphere.The relationship of BC with cloud top temperature and cloud effective radius demonstrates the direct and indirect effect of BC on cloud properties in this region.The RF results reveal that aerosol optical depth has positive aerosol RF in the atmosphere and negative RF at the top of the atmosphere(TOA)as well as at the bottom of the atmosphere(BOA).Negative RF at the TOA indicates less forcing efficiency due to fewer BC aerosols.On the other hand,averaging aerosol RF within the atmosphere reveals positive forcing,which suggests the efficiency force exerted by BC aerosols after absorbing solar radiation.展开更多
基金supported by the National Basic Research Program of China (973 Program, 2015CB856600)the National Natural Science Founda-tion of China (21472004, 21332002)~~
文摘The Cu(I)‐catalyzed cascade coupling/cyclization reaction of N‐tosylhydrazones with 3‐butyn‐1‐ol has been explored. This new strategy represents a simple platform for the synthesis of tetrahydrofurans in moderate to good yields.
基金Supported by the National Natural Science Foundation of China(42050410321)and Key Laboratory of Meteorological Disaster,Ministry of Education(KLME)and Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters(CIC-FEMD),Nanjing University of Information Science&Technology(KLME202210).
文摘Black carbon(BC)is one of the major aerosol components with relatively high implications on climatic patterns through its radiative forcing(RF).South Asia has recently experienced an increased concentration of pollution;however,relatively fewer studies have been carried out on long-term assessment of BC and its implications.The present study analyzed the long-term concentration of BC in selected urban locations over South Asia using the Modern-Era Retrospective analysis for Research and Applications,version 2(MERRA-2).The study employed statistical analysis,including linear regression techniques,to assess the long-term concentration of BC.The results show that a rapid increase of BC is observed over most urban locations of South Asia with the predominance in winter and hence requires strict regional control measures to reduce the excess concentration of BC in the atmosphere.High concentration of BC in winter is attributed to anthropogenic activities and changes in meteorological conditions that enhance the accumulation of pollutants in the atmosphere.The relationship of BC with cloud top temperature and cloud effective radius demonstrates the direct and indirect effect of BC on cloud properties in this region.The RF results reveal that aerosol optical depth has positive aerosol RF in the atmosphere and negative RF at the top of the atmosphere(TOA)as well as at the bottom of the atmosphere(BOA).Negative RF at the TOA indicates less forcing efficiency due to fewer BC aerosols.On the other hand,averaging aerosol RF within the atmosphere reveals positive forcing,which suggests the efficiency force exerted by BC aerosols after absorbing solar radiation.
