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Platinium Nanoparticles Deposited on Oxygen-Containing Functional Groups at Carbon Vulcane XC-72 as a Cathode Catalyst for Direct Methanol Fuel Cell
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作者 Sajjad Sadaghat Sharehjini Ahmad Nozad Golikand mohammad yari 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期840-,共1页
1 Results Surface oxidized carbon vulcane XC-72 as catalyst support, prepared by chemically anchoring Pt onto the surface modified carbon vulcane XC-72. The nanoparticles of Pt are synthesized by reduction of H2PtCl6 ... 1 Results Surface oxidized carbon vulcane XC-72 as catalyst support, prepared by chemically anchoring Pt onto the surface modified carbon vulcane XC-72. The nanoparticles of Pt are synthesized by reduction of H2PtCl6 with sodium borohydride in a 5.5 buffer solution of sodium citrate, the complexation of citrate with metal ions is beneficial to the formation of nanoparticles. For comparison, an electrode is prepared by E-Tek Pt/C 20 Wt% with a typical Pt loading of 50 μg·cm-2, that shows higher specifi... 展开更多
关键词 modified carbon vulcane XC-72 Pt nanoparticles fuel cell methanol electro-oxidation
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Chemically Synthesised Pt Particles on Surface Oxidized Carbon Nanotubes as an Effective Catalyst for Direct Methanol Fuel Cell
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作者 mohammad yari Sajjad Sadaghat Sharehjini 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期838-,共1页
1 Results The synthesis, physical characterization and electrochemical analysis of Pt particles prepared using the surface oxidized carbon nanotubes prepared by chemically anchoring Pt onto the surface of the CNTs wit... 1 Results The synthesis, physical characterization and electrochemical analysis of Pt particles prepared using the surface oxidized carbon nanotubes prepared by chemically anchoring Pt onto the surface of the CNTs with 2.0 mol/L HNO3 by refluxing for 10 h to introduce surface functional groups.The particles of Pt are synthesized by reduction with sodium borohydride of H2PtCl6. The electro-oxidation of liquid methanol of this catalyst as a thin layer on glassy carbon electrode is investigated at room te... 展开更多
关键词 carbon nanotubes Pt particles fuel cell methanol electro-oxidation
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New Synthesis of Pt-Ru Nanoparticles on Surface Modified Carbon Vulcane XC-72 as an Effective Catalyst for Direct Methanol Fuel Cell
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作者 Ahmad Nozad Golikand Sajjad Sadaghat Sharehjini mohammad yari 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期827-,共1页
1 Results Pt-Ru nanoparticles are synthesised on the surface oxidized carbon Vulcane XC-72 as catalyst support by chemically anchoring Pt and Ru onto the surface of modified carbon vulcane XC-72 (by refluxing in 70% H... 1 Results Pt-Ru nanoparticles are synthesised on the surface oxidized carbon Vulcane XC-72 as catalyst support by chemically anchoring Pt and Ru onto the surface of modified carbon vulcane XC-72 (by refluxing in 70% HNO3 at 120 ℃ for 12 h to introduce surface functional groups) .The nanoparticles of Pt and Ru are synthesized by reduction of H2PtCl6 and K4Ru(CN)6 with sodium borohydride in a 5.5 buffer solution of sodium citrate,the complexation of citrate with metal ions is beneficial to the formati... 展开更多
关键词 carbon vulcane XC-72 Pt-Ru nanoparticles fuel cell methanol electro-oxidation
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