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A New Method for the Determination of Cyanide Ions and Their Quantification in Some Senegalese Cassava Varieties
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作者 Younoussa Diallo momar talla gueye +4 位作者 Cheikh Ndiaye Mama Sakho Amadou Kane Jean Paul Barthelemy Georges Lognay 《American Journal of Analytical Chemistry》 2014年第3期181-187,共7页
Cassava (Manihot esculenta Crantz) is a starchy staple food that previous researches have showed to contain cyanogenic compounds, precursors of hydrocyanic acid, undoubtedly toxic for humans. With the aim to determine... Cassava (Manihot esculenta Crantz) is a starchy staple food that previous researches have showed to contain cyanogenic compounds, precursors of hydrocyanic acid, undoubtedly toxic for humans. With the aim to determine food security in cassava, this study developed a simple, fast and less expensive step for quantifying cyanide ions by using micro-diffusion with modified Conway cells. After an enzymatic degradation, the cyanide ions were quantified by electrochemical procedures. The validation of this method is estimated. The concentration of cyanide ions at different part of the samples was determined. The results showed high toxicity in some fresh Senegalese consumed cassava varieties (>100 mg HCN·kg﹣1). However, in the processed cassava products, less than 10 mg HCN·kg﹣1 was found in the different varieties studied except for the chips where the levels of CN﹣ contents were important (>49 mg HCN·kg﹣1). 展开更多
关键词 CASSAVA Cyanogenic GLYCOSIDES CYANIDE Ion Micro-Diffusion TOXICITY
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Development of a Performant Method for Glucocapparin Determination in Boscia senegalensis Lam Ex. Poir.: A Study of the Variability
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作者 momar talla gueye Dogo Seck +5 位作者 Abdoulaye Diallo Danny Trisman Christophe Fischer Jean-Paul Barthelemy Jean-Paul Wathelet Georges Lognay 《American Journal of Analytical Chemistry》 2013年第2期104-110,共7页
This study describes a glucocapparin determination method. Based on rapeseed determination of glucosinolate (GSL), the equation of the average straight regression line is Y = 100.42X – 0.03 (R2 = 0.9998). Enzymatic h... This study describes a glucocapparin determination method. Based on rapeseed determination of glucosinolate (GSL), the equation of the average straight regression line is Y = 100.42X – 0.03 (R2 = 0.9998). Enzymatic hydrolysis of glucocapparin extracted from leaves and fruits of B. senegalensis, analyzed by SPME-GC-MS confirmed the presence of methylisothiocyanate as the main hydrolysis glucocapparin product. Monitoring glucocapparin contents in B. senegalensis leaves and fruits collected in 4 localities in Senegal showed differences between organs according localities and periods of harvest. Glucocapparin content was very high in dry season particularly in January and the lowest rates were recorded during the rainy period between August and November. 展开更多
关键词 Boscia Senegalensis VALIDATION METHOD Glucocapparin Monitoring Senegal
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