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Creep behavior and post-creep thermoelectric performance of the n-type Skutterudite alloy Yb_(0.3)Co_(4)Sb_(12)
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作者 muath m.al malki Xun Shi +2 位作者 Pengfei Qiu G.Jeffrey Snyder David C.Dunand 《Journal of Materiomics》 SCIE EI 2021年第1期89-97,共9页
Upon uniaxial compressive loading at 500℃(T/Tm=0.67,where Tm is the absolute melting point),the n-type Skutterudite alloy Yb03Co4Sb12 deforms plastically by creep via a power-law,with a stress exponent~3 consistent w... Upon uniaxial compressive loading at 500℃(T/Tm=0.67,where Tm is the absolute melting point),the n-type Skutterudite alloy Yb03Co4Sb12 deforms plastically by creep via a power-law,with a stress exponent~3 consistent with dislocation viscous glide.An activation energy of 171 kJ/mol is measured over the temperature range of 500-587℃(T/Tm=0.67-0.75)at a stress of 30 MPa.Yb_(0.3)Co_(4)Sb_(12)is ductile at 500℃,exhibiting a compressive strain of 25%when subjected to stresses ranging from 22 to 90 MPa for up to 28 days.Among the thermoelectric materials tested so far for creep,Yb_(0.3)Co_(4)Sb_(12)exhibits a creep resistance intermediate between low-melting(Bi2Te3,TAGS-85)and high-melting thermoelectrics(Mg2Si and ZrNiSn).A relatively modest drop in the figure of merit zT,from 0.67 to 0.52,is displayed by Yb_(0.3)Co_(4)Sb_(12)after accumulating 3.7%compressive creep strain at 500℃,mostly due to a drop in electrical conductivity. 展开更多
关键词 Filled Skutterudite CoSb_(3) Seebeck coefficient Electrical conductivity CREEP
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