The two three-dimensional oxo-bfidged lanthanides {[Ln2（C4H2O4）3（H20）4]· 3H2O}3, with Ln=Ho3＋ （1）; Gd3＋ （2）, are isomorphous. They have layer-type structures built up from non-centrosymrnetric dinuclear...The two three-dimensional oxo-bfidged lanthanides {[Ln2（C4H2O4）3（H20）4]· 3H2O}3, with Ln=Ho3＋ （1）; Gd3＋ （2）, are isomorphous. They have layer-type structures built up from non-centrosymrnetric dinuclear unit Ln2O12（H2O）4, beside three lattice H20 molecules stabilizing the 3D open-frmnework. The building entities are linked through one classical syn-anti g2-carboxylato-K1O：K^1O＇ bridge. Within the bi-polyhedra, two double μ2-O＇; K2O,O＇ bridges and a syn-syn classical one, support the magnetic measurements carried out on holmium compound indicating relatively weak anti-ferromagnetic interactions. The compari- son with magnetic studies on the almost similar reported Gd（III） compound, suggested that concomitant antiferromagnetic and ferro- magnetic properties could not be excluded. The two distinct thermal behaviors evidenced the higher metal-water bond strength with the smaller cation, and revealed the great supramolecular effects generated by hydrogen-bonding patterns.展开更多
基金Project supported by MESRS-Algeria and MDU-France(project CMEP-Programme Tassili)
文摘The two three-dimensional oxo-bfidged lanthanides {[Ln2（C4H2O4）3（H20）4]· 3H2O}3, with Ln=Ho3＋ （1）; Gd3＋ （2）, are isomorphous. They have layer-type structures built up from non-centrosymrnetric dinuclear unit Ln2O12（H2O）4, beside three lattice H20 molecules stabilizing the 3D open-frmnework. The building entities are linked through one classical syn-anti g2-carboxylato-K1O：K^1O＇ bridge. Within the bi-polyhedra, two double μ2-O＇; K2O,O＇ bridges and a syn-syn classical one, support the magnetic measurements carried out on holmium compound indicating relatively weak anti-ferromagnetic interactions. The compari- son with magnetic studies on the almost similar reported Gd（III） compound, suggested that concomitant antiferromagnetic and ferro- magnetic properties could not be excluded. The two distinct thermal behaviors evidenced the higher metal-water bond strength with the smaller cation, and revealed the great supramolecular effects generated by hydrogen-bonding patterns.
